Charging member, process cartridge and electrophotographic apparatus
AssigneeCanon Kabushiki Kaisha
InventorsKenya Terada, Masaaki Harada, Hiroaki Watanabe, Takumi Furukawa, Keiji Nose
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Abstract
The present invention provides a charging member having an elastic layer on a surface thereof in which occurrence of compression set is reduced. The charging member includes an electro-conductive support and an elastic layer provided on the support as a surface layer, wherein the elastic layer is a rubber layer made of a crosslinked product of a rubber mixture including acrylonitrile butadiene rubber and polybutadiene, the polybutadiene includes 1,2-syndiotactic polybutadiene, and the elastic layer is formed by irradiating a surface of the rubber layer with electron rays.
Claims5
An electrophotographic member comprising:
- an electro-conductive support, and
- an elastic layer provided on the support as a surface layer,
- wherein:
- the elastic layer is formed by irradiating, with electron rays, a rubber layer,
- the rubber layer comprising a crosslinked product of a rubber mixture comprising acrylonitrile butadiene rubber and polybutadiene,
- the polybutadiene includes 1,2-syndiotactic polybutadiene,
- the elastic layer has a higher crosslink density in a surface portion than in an inside portion thereof, the higher crosslink density being due to a cleavage of a 1,2-vinyl bond of the 1,2-syndiotactic polybutadiene with the irradiation of the electron rays,
- a mixing ratio in the rubber mixture between the acrylonitrile butadiene rubber and the polybutadiene is 90 parts by mass:
- 10 parts by mass to 20 parts by mass:
- 80 parts by mass, and
- a content of the 1,2-syndiotactic polybutadiene in the polybutadiene is 3.8 mass % or more and 20 mass % or less.
Dependencies are inferred from the claim text.