Microporous coordination complex and method of making the same
AssigneeThe Regents of the University of Michigan
InventorsAdam J. Matzger, Kyoungmoo Koh
Life of this patent
Estimating the term…
Abstract
Disclosed herein is a three-dimensional coordination complex that includes a plurality of inorganic centers; a plurality of a first bis(bidentate) linker; and a plurality of a second bis(bidentate) linker, where the first and the second bis(bidentate) linkers are have different lengths, and the bidentate binding sites on each linker face in opposite directions on an axis.
Claims35
A three-dimensional coordination complex comprising:
- a plurality of inorganic centers;
- a plurality of a first bis(bidentate) linker having a first length and two bidentate binding sites;
- and
- a plurality of a second bis(bidentate) linker having a second length and two bidentate binding sites,
- wherein each of the first and the second bis(bidentate) linkers is selected from the group consisting of:
- with the following provisos that where the first or second bis(bidentate) linker has the structure of:
- (i) Formula (A), the other linker has the structure of Formula (B);
- (ii) Formula (B), the other linker has the structure of Formula (A) or (C);
- (iii) Formula (C), the other linker has the structure of Formula (B), (D), or (D′);
- (iv) Formula (D) or (D′), the other linker has the structure of Formula (C), (E), or (F);
- (v) Formula (E) or (F), the other linker has the structure of Formula (D), (D′), or (G);
- (vi) Formula (G), the other linker has the structure of Formula (E), (F) or (H);
- and,
- (vii) Formula (H), the other linker has the structure of Formula (G).
A three-dimensional coordination complex comprising:
- a plurality of inorganic centers;
- a plurality of a first bis(bidentate) linker;
- and,
- a plurality of a second bis(bidentate) linker,
- wherein the first bis(bidentate) linker comprises a benzene-1,4-dicarboxylate of formula (I):
- where R is individually selected from the group consisting of NH2, NO2, CH3, Br, Cl, I, and OC1-8H3-17;
- and x is equal to 0, 1, 2, 3, or 4, and
- wherein the second bis(bidentate) linker comprises a naphthalene-2,6-dicarboxylate of formula (J):
- where R is individually selected from the group consisting of NH2, NO2, CH3, Br, Cl, I, and OC1-8H3-17;
- and x is equal to 0, 1, 2, 3, 4, 5, or 6.
A three-dimensional coordination complex comprising:
- a plurality of inorganic centers;
- a plurality of a first bis(bidentate) linker;
- and,
- a plurality of a second bis(bidentate),
- wherein the first bis(bidentate) linker comprises a naphthalene-2,6-dicarboxylate of formula (J):
- where R is selected from the group consisting of NH2, NO2, CH3, Br, Cl, I, and OC1-8H3-17;
- and x is equal to 0, 1, 2, 3, 4, 5, or 6, and
- wherein the second bis(bidentate) linker comprises a biphenyl-4,4′-dicarboxylate of formula (K):
- where R is individually selected from the group consisting of NH2, NO2, CH3, Br, Cl, I, and OC 1-8H3-17;
- and x is equal to 0, 1, 2, 3, or 4.
A crystalline, porous, homogeneous composition comprising:
- a plurality of Zn4O clusters;
- a plurality of benzene-1,4-dicarboxylate each individually bound to the plurality of Zn4O clusters;
- and,
- a plurality of naphthalene-2,6-dicarboxylate each individually bound to the plurality of Zn4O clusters.
A crystalline, porous, homogeneous composition comprising:
- a plurality of Zn4O clusters;
- a plurality of naphthalene-2,6-dicarboxylate each individually bound to the plurality of Zn4O clusters;
- and,
- a plurality of biphenyl-4,4′-dicarboxylate each individually bound to the plurality of Zn4O clusters.
Dependencies are inferred from the claim text.