Polymerizable compositions containing (meth)acrylate monomers having sulfide linkages

A polymerizable composition comprising:

• (a) at least one first (meth)acrylate functional monomer represented by the following Formula (I),
• wherein,
• n is 2,
• L1 is represented by the following Formula (B),
• —(R2—S)p—R3— (B)
• wherein,
• R2 for each p is independently selected from linear or branched optionally substituted C1-C10 alkyl, and optionally substituted C3-C12 cycloalkyl,
• R3 is selected from linear or branched optionally substituted C1-C10 alkyl, and optionally substituted C3-C12 cycloalkyl, and
• p is 0 to 10,
• L2 is independently for each n a divalent optionally substituted hydrocarbyl group optionally interrupted with at least one of —O— and —S—, and
• R1 is independently selected for each n from hydrogen and methyl;
• (b) at least one second (meth)acrylate functional monomer represented by the following Formula (III),
• wherein,
• L4 is a multivalent optionally substituted hydrocarbyl group optionally interrupted with at least one of —C(O)—, —S—, —O— and combinations thereof,
• L5 is independently for each u a divalent optionally substituted hydrocarbyl group, R9 and R10 are each independently selected for each u from hydrogen and methyl, and
• u is from 2 to 6;
• (c) a polymerization moderator comprising at least one of 1-isopropyl-4-methyl-1,4-cyclohexadiene, 1-isopropyl-4-methyl-1,3-cycloheadiene, 1-methyl-4-(propan-2-ylidene)cyclohex-1-ene, 2,6-dimethyl-2,4,6-octatriene, and alpha-methyl styrene dimer;
• and
• (d) optionally, at least one monoethylenically unsaturated monomer.

A polymerizable composition comprising:

• (a) at least one (meth)acrylate functional monomer represented by the following Formula (IV),
• wherein,
• L6 is selected from a multivalent optionally substituted hydrocarbyl group,
• L7 is independently for each v a divalent optionally substituted hydrocarbyl group optionally interrupted with at least one of —O— and —S—,
• R11 is independently selected for each v from hydrogen and methyl,
• v is from 2 to 6,
• R12 is independently for each w divalent optionally substituted hydrocarbyl,
• w is 0 to 10,
• Z is selected from hydrogen or a group represented by the following Formula (V),
• wherein R13 is hydrogen or methyl;
• (b) optionally, a polymerization moderator;
• and
• (c) optionally, at least one monoethylenically unsaturated monomer.

A polymerizable composition comprising:

• (a) at least one (meth)acrylate functional monomer represented by the following Formula (I),
• wherein,
• n is 2,
• each R1 is independently selected from hydrogen and methyl,
• L1 is selected from,
• (i) a divalent linking group represented by the following Formula (D),
• —C(R6)(R7)— (D)
• wherein R6 and R7 are each independently selected from hydrogen, linear or branched optionally substituted C1-C10 alkyl, and optionally substituted C3-C12 cycloalkyl, or R6 and R7 together form a C4-C12 optionally substituted cycloalkyl,
• and
• (ii) a divalent linking group represented by the following Formula (A),
• wherein Y is O or S, and
• (iii) L2 is represented by the following Formula (B),
• —(R2—S)p—R3— (B)
• wherein,
• R2 for each p is independently selected from linear or branched optionally substituted C1-C10 alkyl, and optionally substituted C3-C12 cycloalkyl,
• R3 is selected from linear or branched optionally substituted C1-C10 alkyl, and optionally substituted C3-C12 cycloalkyl, and
• p is 0 to 10;
• (b) at least one second (meth)acrylate functional monomer represented by the following Formula (III),
• wherein,
• L4 is a multivalent optionally substituted hydrocarbyl group optionally interrupted with at least one of —C(O)—, —S—, —O— and combinations thereof,
• L5 is independently for each u a divalent optionally substituted hydrocarbyl group,
• R9 and R10 are each independently selected for each u from hydrogen and methyl, and
• u is from 2 to 6;
• (c) optionally, a polymerization moderator;
• and
• (d) optionally, at least one monoethylenically unsaturated monomer.