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US 9,328,132 B2Granted
Ruthenium complexes, their use in the metathesis reactions, and a process for carrying out the metathesis reaction
AssigneeApeiron Synthesis S.A.
InventorsKrzysztof Skowerski, Michal Bieniek
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Abstract
The invention is related to the metal complexes of the general formula (1). The invention is related also to the use of metal complexes of the formula 1 as (pre)catalysts for the olefin metathesis reactions, as well as to the process for carrying out the olefin metathesis reaction.
Claims19
A complex of the general formula 1:
- wherein,
- X is an anionic ligand;
- Y is oxygen;
- L1 is a neutral ligand other than an N-heterocyclic carbene ligand;
- L2 is an N-heterocyclic carbene ligand;
- R1 is hydrogen, —C1-20 alkyl, —C2-20 alkenyl, —C2-20 alkynyl or —C5-10 aryl;
- and
- R2, R3, R4 and R5 are independently hydrogen, halo, C1-C16 alkyl, C1-C16 alkoxy, C1-C16 perfluoroalkyl, C3-C7 cycloalkyl, C2-C16 alkenyl, C5-C14 aryl, C5-C14 perfluoroaryl, C3-C12 heterocyclyl, —OR6, —NO2, —COOH, —COOR6, —CONR6R7, —SO2NR6R7, —SO2R6, —CHO, —COR6, wherein R6 and R7 are independently C1-C6 alkyl, C1-C6 perfluoroalkyl, C5-C14 aryl, C5-C14 perfluoroaryl;
- or R2, R3, R4 and R5 may be optionally joined together to form a substituted or unsubstituted, fused carbocyclic C4-8 ring, or a substituted or unsubstituted, fused aromatic ring.
6 more elements
Dependencies are inferred from the claim text.