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US 9,328,049 B2Granted
Hydrocarbon conversion process
AssigneeExxonMobil Chemical Patents Inc.
InventorsGary D. Mohr, Paul F. Keusenkothen, Frank Hershkowitz, Jonathan M. McConnachie
Life of this patent
Estimating the term…
Abstract
The invention relates to processes for converting hydrocarbons to phthalic acids such as terephthalic acid. The invention also relates to polymerizing phthalic acid derivatives to produce, e.g., synthetic fibers.
Claims21
A hydrocarbon conversion process, comprising:
- (a) providing a first mixture comprising ≧1.0 wt. % hydrocarbon and ≧1.0 wt. % oxygenate, the weight percents being based on the weight of the first mixture, wherein the oxygenate comprises water obtained from step (d);
- (b) exposing the first mixture to a temperature ≧700° C. under pyrolysis conditions to produce a second mixture, wherein (i) the second mixture comprises ≧1.0 wt. % acetylene based on the weight of the second mixture and (ii) ≧95.0 wt. % of the second mixture's acetylene, based on the weight of the second mixture's acetylene, is produced by conversion of at least a portion of the first mixture's hydrocarbon;
- (c) converting ≧10.0 wt. % of the second mixture's acetylene to cyclooctatetraene, based on the weight of the second mixture's acetylene, in the presence of a catalyst comprising nickel in order to produce a third mixture, the third mixture comprising at least a portion the cyclooctatetraene produced by the acetylene conversion;
- and
- (d) converting ≧5.0 wt. % of the third mixture's cyclooctatetraene to water and phthalic acids, based on the weight of the third mixture's cyclooctatetraene.
2 more elements
Dependencies are inferred from the claim text.