Process for the production of hydrocarbon fluids having a low aromatic content
AssigneeTotal Marketing Services
InventorsChristine Aubry, Joelle Nokerman
Life of this patent
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Abstract
The invention provides a process to prepare very low sulphur, very low aromatic hydrocarbon fluids having a boiling range in the range of from 100 to 400° C. and a boiling range of not more than 80° C., comprising at least the two successive steps of —deep hydrodesulphurating of middle distillate down to less than 10 ppm sulphur, and —catalytic hydrogenating the desulphurized middle distillates of preceding step at a temperature from 80 to 180° C. and at a pressure from 60 to 160 bars.
Claims43
Process to prepare very low sulphur, very low aromatic hydrocarbon fluids containing less than 5 ppm sulphur and having a content in aromatics below 100 ppm, boiling in the range of from 100 to 400° C. and having a boiling range of not more than 80° C., comprising at least the two successive steps of
- deep hydrodesulphurating of middle distillate down to less than 10 ppm sulphur, wherein the deep hydrodesulphurization of middle distillate is operated at a reaction temperature higher than 320° C. under a pressure higher than 70 bars and
- catalytic hydrogenating the desulphurized middle distillates of the preceding step at a temperature from 80 to 180° C. and at a pressure from 60 to 160 bars, with a supported nickel-containing catalyst, a hydrogen treat rate ranging from 100 to 300 Nm3/ton of feed, the catalytic hydrogenation being performed in at least two stages, wherein the first stage operates sulphur trapping on the supported nickel-containing catalyst, hydrogenation of substantially all unsaturated hydrocarbons and up to 90% hydrogenation of aromatics,
- wherein the middle distillate is issued from atmospheric distillation unit effluents or from atmospheric distillation unit and catalytic cracking effluents, such distillates boiling in the range of from 200° C. to 380° C.
Dependencies are inferred from the claim text.