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US 9,315,717 B2Granted
Water-soluble, hydrophobic associating copolymers
AssigneeBASF SE
InventorsThomas Pfeuffer, Roland Reichenbach-Klinke, Stefan Friedrich, Marcus Guzmann
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Abstract
Water-soluble, hydrophobically associating copolymer comprising a monoethylenically unsaturated, water-soluble, surface-active monomer (a), and a monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a). The copolymer is prepared in the presence of a nonpolymerizable surfactant and has marked thickening properties in aqueous systems.
Claims25
A copolymer comprising
- (a) at least one monoethylenically unsaturated, water-soluble, surface-active monomer (a), and
- (b) at least one monoethylenically unsaturated, hydrophilic monomer (b) different from monomer (a),
- wherein the monomer (a) is at least one compound selected from the group consisting of formulae (I), (II) or (III)
- H2C═C(R1)—R4—O—(—CH2—CH2—O—)k—(—CH2—CH(R3)—O—)L—H (I)
- H2C═C(R1)—O—(—CH2—CH2—O—)k—R2 (II) and
- H2C═C(R1)—C═O)—O—(—CH2—CH2—O—)k—R2 (III),
- wherein the units —(—CH2—CH2—O—)k and —(—CH2—CH(R3)—O—)1 are arranged in block structure in the order shown in formula (I) and the radicals and indices are defined as follows:
- k is a number from 6 to 150,
- L is a number from 5 to 25,
- R1 is H or methyl,
- R2 is a hydrocarbon radical having 8 to 40 carbon atoms, wherein the hydrocarbon radical is at least one member selected from the group consisting of aliphatic, aromatic, straight-chain and branched,
- R3 is independently of one another, a hydrocarbon radical having at least 2 carbon atoms,
- R4 is a single bond or a divalent linking group selected from the group of —(CnH2n)—, —O—(Cn′H2′)— and —C(O)—O—(Cn″H2″)— where n, n′ and n″ is in each case a natural number from 1 to 6, and
- wherein during its synthesis, prior to the initiation of the polymerization reaction, at least one further, but nonpolymerizable surface-active compound has been used as further component (c), and wherein the copolymer is a water-soluble, hydrophobically associating copolymer.
11 more elements
Dependencies are inferred from the claim text.