Indicator for cure of two-component-epoxy adhesives
AssigneeHenkel AG & Co. KGaA
InventorsGiorgio Zaffaroni, Antonello Talamini, Monica Noseda
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Abstract
The subject matter of the present application is a cold-curing two-component-epoxy adhesive, comprising (a) an epoxy-resin-component and (b) a curing agent-component, comprising a mercaptan curing agent, in which the epoxy-resin-component comprises a color change indicator. Also described is a method for monitoring the curing progress of cold-curing two-component-epoxy adhesive via color change of the adhesive.
Claims18
Cold-curing two-component-epoxy adhesive, comprising
- (a) an epoxy-resin-component and
- (b) a curing agent-component, comprising a mercaptan curing agent present in a range of 5.0 to 95.0 wt. %, based on the total weight of the curing agent-component (b), yielding a ratio of 1 thiol equivalent of the mercaptan curing agent per 1 to 2 epoxy equivalents of the epoxy-resin-component (a),
- in which the epoxy-resin-component comprises a color change indicator, wherein said cold-curing two-component-epoxy adhesive is capable of curing at a temperature as low as 0° C.
Method for monitoring the curing progress of cold-curing two-component-epoxy adhesive via color change of the adhesive, comprising the mixing of
- (a) an epoxy-resin-component and
- (b) a curing agent-component, comprising a mercaptan curing agent present in a range of 5.0 to 95.0 wt. %, based on the total weight of the curing agent-component (b), yielding a ratio of 1 thiol equivalent of the mercaptan curing agent per 1 to 2 epoxy equivalents of the epoxy-resin-component (a),
- in which the epoxy-resin-component comprises a color change indicator, wherein said cold-curing two-component-epoxy adhesive is capable of curing at a temperature as low as 0° C.
Cold-curing two-component-epoxy adhesive, comprising
- (a) an epoxy-resin-component and
- (b) a curing agent-component, comprising a mercaptan curing agent,
- in which the epoxy-resin-component comprises a color change indicator, wherein said cold-curing two-component-epoxy adhesive is capable of curing at a temperature as low as 0° C.;
- and wherein the color change indicator is selected from the group consisting of Solvent Red 26 {1-[[2,5-dimethyl-4-[(2-methylphenyl)azo]-phenyl]azo]-2-naphthol}, Solvent Red 164 {1-[[4-[phenylazo]-phenyl]azo]-2-naphthol} and combinations thereof.
Cold-curing two-component-epoxy adhesive comprising
- (a) an epoxy-resin-component, comprising:
- (i) at least one polyepoxide, in an amount between 50-80 wt. %,
- (ii) at least one filler, in an amount between of 20-50 wt. %,
- (iii) a color change indicator selected from the group consisting of Solvent Red 26 {1-[[2,5-dimethyl-4-[(2-methylphenyl)azo]-phenyl]azo]-2-naphthol }, Solvent Red 164 {1-[[4-[phenylazo]-phenyl]azo]-2-naphthol} and combinations thereof, in an amount between 0.05% to 5.0% wt. %, said amounts being based on the total weight of the epoxy-resin-component, and
- (b) a curing agent-component, comprising:
- (i) a mercaptan epoxy hardener in amounts of 40-80 wt. %,
- (ii) a tertiary amine, in amounts of 0.1-20 wt. %,
- (iii) at least one filler, in amounts of 20-50 wt. %, said amounts based on the total weight of the curing agent-component.
Cold-curing two-component-epoxy adhesive comprising
- (a) an epoxy-resin-component, comprising:
- (i) a polyepoxide selected from the group consisting of Bisphenol F diglycidyl ether (BFDGE) and Bisphenol A diglycidyl ether (BADGE), in an amount between 50-80 wt. %,
- (ii) quartz powder, in an amount between 20-50 wt. %,
- (iii) a color change indicator selected from the group consisting of Solvent Red 26 {1-[[2,5-dimethyl-4-[(2-methylphenyl)azo]-phenyl]azo]-2-naphthol }, Solvent Red 164 {1-[[4-[phenylazo]-phenyl]azo]-2-naphthol} and combinations thereof, in an amount between 0.05% to 5.0% wt. %, said amounts are based on the total weight of the epoxy-resin-component, and
- (b) curing agent-component, comprising:
- (i) a mercaptan epoxy hardener in an amount between 40-80wt. %,
- (ii) Tris(dimethylaminomethyl)phenol, in an amount between 0.1-20 wt. %,
- (iii) quartz powder, in an amount between of 20-50 wt. %, said amounts based on the total weight of the curing agent-component.
Dependencies are inferred from the claim text.