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US 9,314,408 B2Granted
Dental composite materials comprising tricyclic plasticizers
AssigneeVOCO GmbH
InventorsTobias Blomker, Nils Fontein, Manfred Stepputtis, Manfred Thomas Plaumann
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Abstract
The present invention relates to dental polymerizable composite materials (curable dental compositions) comprising one or more plasticizers comprising a tricyclic structural element, to dental materials (polymers), obtainable by curing from the dental polymerizable composite materials comprising one or more plasticizers comprising a tricyclic structural element, to processes for producing a dental material and to dental curable composite materials for use in a therapeutic method in the production of a dental material.
Claims21
A dental curable composite material comprising
- (a) one or more compound(s) of the structure Q-[(Y)n-X]o which are not free-radically polymerizable during curing with constituent (b), wherein:
- Q is a tricyclic structural element wherein one, two or more of the hydrogen atoms not substituted by Yn-X substituents in this tricyclic structural element Q are optionally replaced by alkyl groups, alkoxy groups, halogen atoms or trifluoromethyl groups;
- Y is methylene (—CH2—);
- n =0 or 1;
- X is selected from the group consisting of —O—Z, —N—(Z)2, —NH—Z, —O—C(═O)—Z, —C(═O)—O—Z, —O—C(═O)—NH—Z, —NH—C(═O)—O —Z, —NH—C(═O)—NH—Z, —C(═O)—NH—Z, —NH—C(═O)—Z, —C(═O)—N—(Z)2, —N—(Z) —C(═O)—Z, —O—C(═O)—N(Z)—C(═O)—NH—Z,—NH—C(═O)—N(Z)—C(═O)—NH—Z, —N(C(═O)—NH—Z)2, —C(═O)—N(Z)—C(═O)—NH—Z,—N(C(═O)—NH—Z)(C(═O)—Z), and —N(C(═O)—NH—Z)(C(═O)—O—Z), wherein the bond arranged on the left in each formula is closer to the structural element Q and wherein X is selected such that Z has a minimum number of atoms,
- Z is an organic radical having at least one carbon atom, and each Z may be the same or different, and
- o =2, 3, or 4, and
- (b) further constituents comprising
- (b-1) one or more different monomer(s) selected from the group consisting of (meth)acrylates,
- (b-2) one or more fillers, and
- (b-3) one or more photoinitiator(s) and/or one or more initiator(s) for chemical curing.
8 more elements
Dependencies are inferred from the claim text.