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US 9,309,402 B2Granted
Biodegradable resin composition and molded article of the same
AssigneeMitsui Chemicals, Inc.
InventorsShintaro Maekawa, Shinichi Usugi, Hitoshi Onishi
Life of this patent
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Abstract
Disclosed are a biodegradable resin composition comprising a copolymer (A) with a weight average molecular weight of 1,000 to 30,000, which comprises a constituent unit (a-1) derived from a multivalent carboxylic acid except for an amino acid and a constituent unit (a-2) derived from a hydroxycarboxylic acid, and a biodegradable resin (B), which has excellent hydrolyzability and excellent transparency; and a biodegradable molded article composed of this biodegradable resin composition.
Claims8
A biodegradable resin composition, comprising:
- a copolymer (A) with a weight average molecular weight of 2,500 to 20,000, which comprises a constituent unit (a-1) derived from a hydroxydicarboxylic acid and a hydroxytricarboxylic acid and a constituent unit (a-2) derived from a hydroxycarboxylic acid or a hydroxy carboxylic acid derivative selected from glycolic acid, lactic acid, 2-hydroxybutyric acid, 2-hydroxyvaleric acid, 2-hydroxycaproic acid, 2-hydroxycapric acid, glycolide, lactide, p-dioxanone, β-propiolactone, β-butyrolactone, δ-valerolactone or ε-caprolactone, and
- a biodegradable resin (B) that is different from the copolymer (A),
- wherein the copolymer is obtained by mixing the hydroxydicarboxylic acid and the hydroxytricarboxylic acid and the hydroxycarboxylic acid or hydroxycarboxylic acid derivative and by carrying out dehydration condensation polymerization under heat and reduced pressure in the presence or absence of a catalyst, and
- wherein the mol composition ratio [(a-1)/(a-2)] of constituent unit (a-1) and constituent unit (a-2) in copolymer (A) is 1/10 to 1/50, and
- wherein a constituent unit other than the constituent units (a-1) and (a-2) in the copolymer (A) is 20 mol % or less, and
- wherein the biodegradable resin composition has a weight average molecular weight of 50,000 to 1,000,000.
3 more elements
Dependencies are inferred from the claim text.