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US 9,308,156 B2Granted
Blends of O-acyl-isethionates and N-acyl amino acid surfactants
AssigneeGalaxy Surfactants Ltd.
InventorsNirmal Koshti, Bhagyesh Jagannath Sawant
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Abstract
The present invention discloses a process for preparing blends of O-acyl isethionates and N-acyl amino acid surfactants using common fatty acid chlorides, in quantitative yields. The blends are in liquid form or can be spray dried to obtain solid dried form.
Claims8
A process of producing an aqueous blend of an O-acyl isethionate of Formula I, and an N-acyl amino acid based surfactant of Formula II,
- wherein:
- R is selected from the group consisting of saturated and unsaturated C5 to C21 alkyl groups,
- R1 is selected from the group consisting of H and C1 to C4 alkyl,
- R2 is hydrogen, or R2 is an organic group having a structure which corresponds to a side chain bound to an α-carbon of a naturally occurring α-amino acid,
- R3 is selected from the group consisting of COOX and CH2-SO3X, where X is selected from the group consisting of Li+, Na+ and K+,
- R4 is selected from the group consisting of H and methyl, and
- M is a cation selected from Na+, K+, NH4+, and a quaternary ammonium cation derived from a tertiary amine,
- said method comprising:
- A) reacting more than one equivalent of a fatty acid chloride with alkali metal or ammonium salts of a hydroxyalkyl sulphonate to obtain a compound of Formula I, and
- B) reacting unreacted fatty acid chloride in the product of step (A) with an amino acid reactant in the presence of a base under aqueous Schotten Baumann reaction conditions to yield compounds of Formula II.
7 more elements
Dependencies are inferred from the claim text.