Back to results
US 9,302,259 B2Granted
Solid base catalyst and method for making and using the same
AssigneeJiangsu Sinorgchem Technology Co., Ltd.
InventorsXinmin Chen, Jianliang Zhu
Life of this patent
Estimating the term…
Abstract
A solid base catalyst having a carrier, an organic base, and an inorganic base. Both of the organic base and inorganic base are loaded on the carrier. The solid base catalyst is especially suitable for the synthesis of 4-Aminodiphenylamine (4-ADPA).
Claims11
A solid base catalyst comprising
- an organic base,
- an inorganic base;
- and
- a carrier,
- wherein the organic base is polymerized with the carrier, and the inorganic base is physically adsorbed in the carrier to regenerate the organic base in situ;
- and
- the carrier is a macroporous strong basic anion-exchange styrene resin that is D201 or its equivalent Amberlite IRA900 resin having a matrix structure of a copolymerized styrene—DVB gel resin, a functional group of —N+(CH3)3, an appearance of milky white opaque spherical particles, being shipped in a Cl-ionic form, having a strong group of capacity of equal to or more than 3.7 mmol/g when dry in the Cl-ionic form, a total exchange capacity in volume of equal to or more than 1.15 mmol/mL in the Cl-ionic form, a moisture holding capacity of 50-60% in the Cl-ionic form, a specific gravity of 1.06 g/mL to 1.10 g/mL in the Cl-ionic form, a shipping weight of 0.65 g/mL to 0.73 g/mL in the Cl-ionic form, a harmonic mean size of 0.40 mm to 0.70 mm, a particle size of 0.315 mm to 1.25 mm for equal to or more than 95% of the particles and less than 0.315 mm for less than 1% of the particles, a uniformity coefficient of equal to or less than 1.6, an osmotic-attrited of equal to or more than 90%, and a maximum reversible swelling of Cl—OH— at 25%.
4 more elements
Dependencies are inferred from the claim text.