Pre calcination additives for mixed metal oxide ammoxidation catalysts
AssigneeIneos USA LLC
InventorsJames Frank Brazdil, Charles James Besecker, Michael J. Seely, Muin S. Haddad, Mark A. Toft
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Abstract
A process for preparation of catalysts for the production of acrylonitrile, acetonitrile and hydrogen cyanide comprising contacting at an elevated temperature, propylene, ammonia and oxygen in the vapor phase in the presence of a catalyst, said catalyst comprising a complex of metal oxides wherein a heat-decomposable nitrogen containing compound is added during the process for the preparation of the catalyst.
Claims15
A process for the conversion of an olefin selected from the group consisting of propylene, isobutylene and mixtures thereof, to acrolein/acrylic acid, methacrolein/methacrylic acid, and mixtures thereof, respectively, by reacting in the vapor phase at an elevated temperature and pressure said olefin with a molecular oxygen containing gas in the presence of a catalyst wherein the relative ratios of the elements in said catalyst are represented by the following formula:
- Mo12BiaFebAcDdEeFfGgCehOx
- wherein
- A is at least one element selected from the group consisting of sodium, potassium, rubidium and cesium;
- and
- D is at least one element selected from the group consisting of nickel, cobalt, manganese, zinc, magnesium, calcium, strontium, cadmium and barium;
- E is at least one element selected from the group consisting of chromium, tungsten, boron, aluminum, gallium, indium, phosphorus, arsenic, and vanadium;
- F is at least one element selected from the group consisting of lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium thulium, ytterbium, lutetium, scandium, yttrium, titanium, zirconium, hafnium, niobium, tantalum, aluminum, gallium, indium, thallium, silicon, germanium, and lead;
- G is at least one element selected from the group consisting of silver, gold, ruthenium, rhodium, palladium, osmium, iridium, platinum and mercury;
- and
- a is from 0.05 to 7,
- b is from 0.1 to 7,
- c is from 0.01 to 5,
- d is from 0.1 to 12,
- e is from 0 to 5,
- f is from 0 to 5,
- g is from 0 to 0.2,
- h is from 0.01 to 5, and
- x is the number of oxygen atoms required to satisfy the valence requirements of the other component elements present;
- wherein 0.8≦h/b≦5;
- and
- wherein the process for the preparation of the catalyst comprises the addition of at least one heat-decomposable nitrogen-containing compound selected from the group consisting of ammonium compounds, nitrate compounds, nitrite compounds, amide compounds, nitro benzoic compounds, and ammonium hydroxide compounds.
A process for the conversion of an olefin selected from the group consisting of propylene, isobutylene and mixtures thereof, to acrylonitrile, methacrylonitrile, and mixtures thereof, respectively, by reacting in the vapor phase at an elevated temperature and pressure said olefin with a molecular oxygen containing gas and ammonia in the presence of a catalyst wherein the relative ratios of the elements in said catalyst are represented by the following formula:
- Mo12BiaFebAcDdEeFfGgCehOx
- wherein A is at least one element selected from the group consisting of sodium, potassium, rubidium and cesium;
- and
- D is at least one element selected from the group consisting of nickel, cobalt, manganese, zinc, magnesium, calcium, strontium, cadmium and barium;
- E is at least one element selected from the group consisting of chromium, tungsten, boron, aluminum, gallium, indium, phosphorus, arsenic, and vanadium;
- F is at least one element selected from the group consisting of lanthanum, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium thulium, ytterbium, lutetium, scandium, yttrium, titanium, zirconium, hafnium, niobium, tantalum, aluminum, gallium, indium, thallium, silicon, germanium, and lead;
- G is at least one element selected from the group consisting of silver, gold, ruthenium, rhodium, palladium, osmium, iridium, platinum and mercury;
- and
- a is from 0.05 to 7,
- b is from 0.1 to 7,
- c is from 0.01 to 5,
- d is from 0.1 to 12,
- e is from 0 to 5,
- f is from 0 to 5,
- g is from 0 to 0.2,
- h is from 0.01 to 5, and
- x is the number of oxygen atoms required to satisfy the valence requirements of the other component elements present;
- wherein 0.8≦h/b≦5;
- and
- wherein the process for the preparation of the catalyst comprises the addition of at least one heat-decomposable nitrogen-containing compound selected from the group consisting of ammonium compounds, nitrate compounds, nitrite compounds, amide compounds, nitro benzoic compounds, and ammonium hydroxide compounds.
Dependencies are inferred from the claim text.