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US 9,290,611 B2Granted
Production and use of polymers comprising hydroxyl groups and acrylate groups
AssigneeBASF SE
InventorsHarm-Anton Klok, Sanhao Ji, Bernd Bruchmann, Christine Roesch
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Abstract
The present invention relates to polymers which contain hydroxyl groups and acrylate groups, to processes for preparing them, and to their use.
Claims34
A polymer, comprising:
- a hydroxyl group;
- and
- an acrylate group;
- wherein:
- the polymer is a reaction product of a dicarbonyl compound with a diacrylate compound;
- the dicarbonyl compound comprises just two carbonyl groups, each independently selected from the group consisting of an aldehyde group and a keto group, bonded to one another through a substituted or unsubstituted C1-C8-alkyl, a substituted or unsubstituted C2-C8-alkenyl, a substituted or unsubstituted carboxy-C1-C8-alkyl, a substituted or unsubstituted C6-C12-aryl, a substituted or unsubstituted C6-C12-arylene, a substituted or unsubstituted C3-C12-cycloalkylene, or a substituted or unsubstituted C1-C20-alkylene;
- and
- the dicarbonyl compound and the diacrylate compound are reacted in the presence of at least one tertiary amine or phosphine selected from the group consisting of trimethylamine, triethylamine, tri-n-butylamine, ethyldiisopropylamine, methyldiisopropylamine, N-methylmorpholine, N-methylpiperidine, triethanolamine, N,N-dimethylethanolamine, 2 dimethylaminopyridine, 4-dimethylaminopyridine, diazabicyclooctane, 1,5 diazabicyclo[4.3.0]non-5-ene (DBN), 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), pyrrocoline, quinuclidine, quinidine, trimethylphosphine, triethylphosphine, tri-n butylphosphine, dimethylphenylphosphine, and 1,4 diazabicyclo[2.2.2]octane (DABCO).
5 more elements
A polymer, comprising:
- a hydroxyl group;
- and
- an acrylate group;
- wherein:
- the polymer is a reaction product of a dialdehyde compound with a diacrylate compound;
- and
- the dialdehyde compound is of formula:
- OHC—R1—CHO
- wherein R1 is an unsubstituted C6-C12-arylene or an unsubstituted C2-C20-alkylene.
6 more elements
Dependencies are inferred from the claim text.