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US 9,287,597 B2Granted
Ionic liquid containing hydroxamate and N-alkyl sulfamate ions
AssigneeFluidic, Inc.
InventorsCody A. Friesen, Derek Wolfe, Paul Bryan Johnson
Life of this patent
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Abstract
Embodiments of the invention are related to ionic liquids and more specifically to ionic liquids used in electrochemical metal-air cells in which the ionic liquid includes a cation and an anion selected from hydroxamate and/or N-alkyl sulfamate anions.
Claims14
An ionic liquid comprising a cation and an anion selected from hydroxamate and N-alkyl sulfamate anions, wherein the hydroxamate anion has the following general formula:
- wherein R is selected from hydrogen, linear or branched, saturated or unsaturated, aliphatic or alicyclic alkyl groups having 1 to 30 carbon atoms;
- oligoethylene glycol monoalkyl ethers of the form (R′—(O—CH2—CH2)p—O—CH2—CH2), wherein p represents a number of from 1 to 30 and R′ represents a linear or branched, saturated or unsaturated, aliphatic or alicyclic alkyl group having 1 to 30 carbon atoms;
- alkenyl;
- cycloalkyl;
- heteroaryl-C1-6-alkyl groups having from 3 to 8 carbon atoms in the aryl residue and at least one heteroatom selected from N, O, P, and S which may be substituted with at least one C1-6 alkyl group and/or halogen atoms;
- and aryl-C1-6-alkyl groups having from 5 to 12 carbon atoms in the aryl residue which may be optionally substituted with at least one C1-6 alkyl group and/or halogen atom;
- and
- the N-alkyl sulfamate anion has the following general formula:
- wherein R is selected from linear or branched, saturated or unsaturated, aliphatic or alicyclic alkyl groups having 1 to 30 carbon atoms;
- oligoethylene glycol monoalkyl ethers of the form (R′—(O—CH2—CH2)p—O—CH2—CH2), wherein p represents a number of from 1 to 30 and R′ represents a linear or branched, saturated or unsaturated, aliphatic or alicyclic alkyl group having 1 to 30 carbon atoms;
- alkenyl;
- heteroaryl-C1-6-alkyl groups having from 3 to 8 carbon atoms in the aryl residue and at least one heteroatom selected from N, O, P, and S which may be substituted with at least one C1-6 alkyl group and/or halogen atoms;
- aryl-C1-6-alkyl groups having from 5 to 12 carbon atoms in the aryl residue which may be optionally substituted with at least one C1-6 alkyl group and/or halogen atom.
10 more elements
An electrochemical cell comprising:
- a) a fuel electrode for oxidizing a fuel;
- b) an air electrode configured to absorb and reduce gaseous oxygen;
- and
- c) an ionic liquid comprising a cation and an anion selected from hydroxamate and N-alkyl sulfamate anions.
1 more element
Dependencies are inferred from the claim text.