Pre-reformer for selective reformation of higher hydrocarbons

An anode recuperator for a fuel cell system, comprising:

• a first annular fuel passage, wherein an inner wall of the first annular fuel passage is configured to form an upper plenum surrounded by the first annular fuel passage;
• an annular pre-reformer coupled to the first annular fuel passage and configured to receive an unreformed fuel stream from the first annular fuel passage and at least partially reform the unreformed fuel stream to generate a reformed fuel stream, the annular pre-reformer located axially inward of the first annular fuel passage;
• and
• an annular anode exhaust passage surrounding at least a portion of the first annular fuel passage and the annular pre-reformer, the annular anode exhaust passage thermally coupled to the first annular fuel passage such that an anode exhaust stream in the annular anode exhaust passage provides heat to the unreformed fuel stream in the first annular fuel passage,
• wherein the annular pre-reformer is separated from the annular anode exhaust passage;
• further comprising a second annular fuel passage coupled to the annular pre-reformer and configured to receive the reformed fuel stream from the annular pre-reformer;
• wherein:
• an inner wall of the second annular fuel passage is configured to form a lower plenum surrounded by the second annular fuel passage;
• the annular anode exhaust passage surrounds at least a portion of the second annular fuel passage and the annular anode exhaust passage is thermally coupled to the second annular fuel passage such that the anode exhaust stream in the annular anode exhaust passage provides heat to the reformed fuel stream in the second annular fuel passage;
• and
• the annular pre-reformer is separated from the annular anode exhaust passage by the first annular fuel passage or the second annular fuel passage;
• and
• wherein:
• the annular pre-reformer includes a first annular pre-reforming passage and a second annular pre-reforming passage, the first annular pre-reforming passage encircling the second annular pre-reforming passage;
• and
• the second annular pre-reforming passage is configured to receive the unreformed fuel stream from the first annular fuel passage and the first annular pre-reforming passage is configured to provide the reformed fuel stream to the second annular fuel passage.

An anode recuperator for a fuel cell system, comprising:

• a first annular fuel passage, wherein an inner wall of the first annular fuel passage is configured to form an upper plenum surrounded by the first annular fuel passage;
• an annular pre-reformer coupled to the first annular fuel passage and configured to receive an unreformed fuel stream from the first annular fuel passage and at least partially reform the unreformed fuel stream to generate a reformed fuel stream, the annular pre-reformer located axially inward of the first annular fuel passage;
• and
• an annular anode exhaust passage surrounding at least a portion of the first annular fuel passage and the annular pre-reformer, the annular anode exhaust passage thermally coupled to the first annular fuel passage such that an anode exhaust stream in the annular anode exhaust passage provides heat to the unreformed fuel stream in the first annular fuel passage,
• wherein the annular pre-reformer is separated from the annular anode exhaust passage;
• and
• wherein:
• the annular pre-reformer includes a first annular pre-reforming passage and a second annular pre-reforming passage, the first annular pre-reforming passage encircling the second annular pre-reforming passage;
• the first annular pre-reforming passage is configured to receive the unreformed fuel stream from the first annular fuel passage and the second annular pre-reforming passage is configured to provide the reformed fuel stream to an anode feed manifold;
• and
• a pre-reformer catalyst is located only in the second annular pre-reformer passage and is not located in the first annular pre-reforming passage.

A method of operating an anode recuperator of a fuel cell system, comprising:

• pre-reforming an unreformed fuel stream at a temperature less than or equal to 750 degrees Celsius to selectively reform higher hydrocarbons in the unreformed fuel stream over methane in the unreformed fuel stream to generate a reformed fuel stream;
• providing the unreformed fuel stream from a first annular fuel passage to an annular pre-reformer, wherein an inner wall of the first annular fuel passage is configured to form an upper plenum surrounded by the first annular fuel passage and the annular pre-reformer is coupled to the first annular fuel passage;
• at least partially reforming the unreformed fuel stream in the annular pre-reformer to generate the reformed fuel stream;
• providing an anode exhaust stream in an annular anode exhaust passage to provide heat to the unreformed fuel stream in the first annular fuel passage, the annular anode exhaust passage surrounding at least a portion of the first annular fuel passage and the annular pre-reformer;
• providing the reformed fuel stream to a second annular fuel passage coupled to the annular pre-reformer, wherein an inner wall of the second annular fuel passage is configured to form a lower plenum surrounded by the second annular fuel passage;
• and
• providing the anode exhaust stream in the annular anode exhaust passage to provide heat to the reformed fuel stream in the second annular fuel passage, the annular anode exhaust passage surrounding at least a portion of the second annular fuel passage;
• wherein the annular pre-reformer is located axially inward of the first annular fuel passage and the annular pre-reformer is separated from the annular anode exhaust passage by the first annular fuel passage or the second annular fuel passage;
• and
• wherein the annular pre-reformer includes a first annular pre-reforming passage and a second annular pre-reforming passage, the first annular pre-reforming passage encircling the second annular pre-reforming passage, the method further comprising:
• receiving the unreformed fuel stream from the first annular fuel passage in the first annular pre-reforming passage;
• and
• providing the reformed fuel stream to the second annular fuel passage from the second annular pre-reforming passage.

A method of operating an anode recuperator of a fuel cell system, comprising:

• pre-reforming an unreformed fuel stream at a temperature less than or equal to 750 degrees Celsius to selectively reform higher hydrocarbons in the unreformed fuel stream over methane in the unreformed fuel stream to generate a reformed fuel stream;
• providing the unreformed fuel stream from a first annular fuel passage to an annular pre-reformer, wherein an inner wall of the first annular fuel passage is configured to form an upper plenum surrounded by the first annular fuel passage and the annular pre-reformer is coupled to the first annular fuel passage;
• at least partially reforming the unreformed fuel stream in the annular pre-reformer to generate the reformed fuel stream;
• providing an anode exhaust stream in an annular anode exhaust passage to provide heat to the unreformed fuel stream in the first annular fuel passage, the annular anode exhaust passage surrounding at least a portion of the first annular fuel passage and the annular pre-reformer;
• providing the reformed fuel stream to a second annular fuel passage coupled to the annular pre-reformer, wherein an inner wall of the second annular fuel passage is configured to form a lower plenum surrounded by the second annular fuel passage;
• and
• providing the anode exhaust stream in the annular anode exhaust passage to provide heat to the reformed fuel stream in the second annular fuel passage, the annular anode exhaust passage surrounding at least a portion of the second annular fuel passage;
• wherein the annular pre-reformer is located axially inward of the first annular fuel passage and the annular pre-reformer is separated from the annular anode exhaust passage by the first annular fuel passage or the second annular fuel passage;
• and
• wherein the annular pre-reformer includes a first annular pre-reforming passage and a second annular pre-reforming passage, the first annular pre-reforming passage encircling the second annular pre-reforming passage, the method further comprising:
• receiving the unreformed fuel stream from the first annular fuel passage in the second annular pre-reforming passage;
• and
• providing the reformed fuel stream to the second annular fuel passage from the first annular pre-reforming passage.

A method of operating an anode recuperator of a fuel cell system, comprising:

• pre-reforming an unreformed fuel stream at a temperature less than or equal to 750 degrees Celsius to selectively reform higher hydrocarbons in the unreformed fuel stream over methane in the unreformed fuel stream to generate a reformed fuel stream;
• providing the unreformed fuel stream from a first annular fuel passage to an annular pre-reformer, wherein an inner wall of the first annular fuel passage is configured to form an upper plenum surrounded by the first annular fuel passage and the annular pre-reformer is coupled to the first annular fuel passage;
• at least partially reforming the unreformed fuel stream in the annular pre-reformer to generate the reformed fuel stream;
• and
• providing an anode exhaust stream in an annular anode exhaust passage to provide heat to the unreformed fuel stream in the first annular fuel passage, the annular anode exhaust passage surrounding at least a portion of the first annular fuel passage and the annular pre-reformer;
• and
• wherein:
• the annular pre-reformer is located axially inward of the first annular fuel passage;
• the annular pre-reformer is separated from the annular anode exhaust passage;
• and
• the annular pre-reformer includes a first annular pre-reforming passage and a second annular pre-reforming passage, the first annular pre-reforming passage encircling the second annular pre-reforming passage,
• the method further comprising:
• receiving the unreformed fuel stream from the first annular fuel passage in the first annular pre-reforming passage;
• receiving the unreformed fuel stream in the second annular pre-reforming passage from the first annular pre-reforming passage;
• at least partially reforming the unreformed fuel stream in the second annular pre-reforming passage to generate the reformed fuel stream;
• and
• providing the reformed fuel stream to an anode feed manifold from the second annular pre-reforming passage,
• wherein a pre-reformer catalyst is located only in the second annular pre-reformer passage and is not located in the first annular pre-reforming passage.