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US 9,259,380 B2Granted
Means for dyeing and/or matting keratinic fibres containing novel 1,4 diaminoanthraquinone dyes
AssigneeHenkel AG & Co. KGaA
InventorsAntje Gebert, Astrid Kroos, Ralph Nemitz
Life of this patent
Estimating the term…
Abstract
Agents for coloring and/or matting keratinic fibers, in particular human hair, include in a cosmetic carrier at least one specific substituted 1,4-diaminoanthraquinone derivative of formula (I), wherein the residues (R2, R4) mutually independently denote a grouping of formula (II). The cosmetic method of using these agents can be for producing intense blue shades and for matting keratin fibers.
Claims9
An agent for coloring and/or matting keratinic fibers, including in a cosmetic carrier at least one 1,4-diaminoanthraquinone derivative selected from the group consisting of
- 1,4-bis[(2-methoxyethyl)amino]-9,10-dihydroanthracene-9,10-dione
- 1,4-bis[(2-ethoxyethyl)amino]-9,10-dihydroanthracene-9,10-dione
- 1,4-bis[2-propoxyethyl)amino]-9,10-dihydroanthracene-9,10-dione
- 1,4-bis[(3-methoxypropyl)amino]-9,10-dihydroanthracene-9,10-dione
- 1,4-bis[(3-ethoxypropyl)amino]-9,10-dihydroanthracene-9,10-dione
- 1,4-bis[(3-propoxypropyl)amino]-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis[(2-methoxyethyl)amino]-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis[(2-ethoxyethyl)amino]-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis[(2-propoxyethyl)amino]-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis[(3-methoxypropyl)amino]-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis[(3-ethoxypropyl)amino]-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis[(3-propoxypropyl)amino]-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({[2-(2-hydroxyethoxyl)ethyl]amino})-9,10-dihydro anthracene-9,10-dione
- 1,4-bis({[3-(2-hydroxyethoxy)propyl]amino})-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({[2-(3-hydroxypropoxy)ethyl]amino})-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({[3-(3-hydroxypropoxyl)propyl]amino})-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis({[2-(2-hydroxyethoxy)ethyl]amino})-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis({[3-(2-hydroxyethoxy)propyl]amino})-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis({[3-(3-hydroxypropoxy)ethyl]amino})-9,10-dihydroanthracene-9,10-dione
- 6-methoxy-1,4-bis({[3-(3-hydroxypropoxy)propyl]amino})-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({2-[(2-hydroxyethyl)amino]ethyl}amino)-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({2-[(3-hydroxypropyl)amino]ethyl}amino)-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({3-[(2-hydroxyethyl)amino]propyl}amino)-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({3-[(3-hydroxypropyl)amino]propyl}amino)-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({2-[(2-aminoethyl)amino]ethyl}amino)-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({2-[(3-aminopropyl)amino]ethyl}amino)-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({3-[(2-aminoethyl)amino]propyl}amino)-9,10-dihydroanthracene-9,10-dione
- 1,4-bis({3-[(3-aminopropyl)amino]propyl}amino)-9,10-dihydroanthracene-9,10-dione
- N-methyl-3-[(4-{[2-(methylcarbamoyl)ethyl]amino}-9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]propanamide
- N-methyl-4-[(4-{[3-(methylcarbamoyl)propyl]amino}-9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]butanamide
- N-ethyl-3-[(4-{[2-(ethylcarbamoyl)ethyl]amino}-9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]propanamide
- N;N-dimethyl-3-[(4-{[2-(dimethylcarbamoyl)ethyl]amino}-9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]propanamide and
- N;N-diethyl-3-[(4-{[2-(diethylcarbamoyl)ethyl]amino}-9,10-dioxo-9,10-dihydroanthracen-1-yl)amino]propanamide.
30 more elements
A method for matting keratinic fibers in which, directly before use,
- a cosmetic agent (A1) for oxidative lightening including 0.5 to 20 wt. % hydrogen peroxide is mixed with
- an agent (A2),
- this ready-to-use agent is applied onto the keratin fibers, left on the keratin fibers for a period of 5 to 60 minutes, and then rinsed back out, and
- then a post-treatment agent (B) is applied onto the keratin fibers, left on the keratin fibers for a period of 2 to 45 minutes, and then rinsed back out,
- wherein the agent (A2) and/or the agent (B) includes in a cosmetic carrier at least one 1,4-diaminoanthraquinone derivative of formula (I),
- in which
- R1, R3 mutually independently denote a hydrogen atom, a C1-C6 alkyl group, a C2-C6 alkenyl group, a hydroxy-C2-C6-alkyl group, a polyhydroxy-C2-C6-alkyl group, a cyano-C1-C6-alkyl group, a halo-C1-C6-alkyl group, an aryl-C1-C6-alkyl group, a heteroaryl-(C1-C6)-alkyl group, an aryl group, a heteroaryl group, an amino-(C2-C6)-alkyl group, a C1-C6-alkylamino-C2-C6-alkyl group or a C1-C6-dialkylamino-C2-C6-alkyl group,
- R2, R4 mutually independently denote a grouping of formula (II),
- —(CH2)n—Y1-(CH2)m—Y2 (II)
- in which
- Y1 denotes an oxygen atom (—O—), a sulfur atom (—S—), an amide group —CONR5- or a group —NR5-,
- Y2 denotes a hydrogen atom, a C2-C6 alkenyl group, a hydroxyl group, a C1-C6 alkoxy group, a hydroxy-C2-C6-alkoxy group or a group —NR5R6,
- n denotes an integer from 2 to 6,
- m denotes an integer from 1 to 6,
- R5, R6 mutually independently denote a hydrogen atom, a C1-C6 alkyl group, a C2-C6 alkenyl group, or a hydroxy-C2-C6-alkyl group, and
- X1, X2 mutually independently denote a hydrogen atom, a hydroxyl group, a C1-C6 alkoxy group, a C1-C6 alkyl group, a C2-C6 alkenyl group, a hydroxy-C2-C6-alkyl group, a polyhydroxy-C2-C6-alkyl group, a cyano-C1-C6-alkyl group, an amino group, a C1-C6-alkylamino group, a di-C1-C6-alkylamino group, an amino-(C2-C6)-alkyl group, a C1-C6-alkylamino-C2-C6-alkyl group, a di-C1-C6-alkylamino-C2-C6-alkyl group, a C1-C6-alkoxy-C2-C6-alkyl group, a C1-C6-alkoxy-C2-C6-alkyloxy group, a nitro group, a carboxy group, a sulfonic acid group or a halogen atom.
13 more elements
Dependencies are inferred from the claim text.