Conjugated polymer compound
AssigneeNational Chiao Tung University
InventorsChain-Shu Hsu, Ching-Yao Lin, Chien-Lung Wang, Jhong-Sian Wu, Yi-Hsiang Chao, Jyun-Fong Jheng, Ming-Chi Tsai, Chin-Li Wang
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Abstract
A conjugated polymer compound is disclosed. The conjugated polymer compound includes a conjugated polymeric main chain; and a porphyrin compound having absorption in a blue light region of solar radiation, and is bonded to the polymeric main chain to form a side chain on the polymeric main chain.
Claims15
A conjugated polymer compound having one of the formula (1) and (2),
- wherein each of A and D is one selected from a group consisting of an unsaturated 5-membered heterocyclic ring, an unsaturated 6-membered heterocyclic ring, an unsaturated 5-membered heteroaromatic ring and an unsaturated 6-membered heteroaromatic ring, each of a and b ranges from 1 to 20, n ranges from 1 to 100, the Por is a porphyrin compound, and π is selected from one of an unsaturated C3-16 aromatic ring and an unsaturated C3-16 heteroaromatic ring, wherein the unsaturated C3-16 heteroaromatic ring includes at least a heteroatom, and the heteroatom includes at least one selected from a group consisting of N, S, O, and Se.
A conjugated polymer compound, comprising:
- a conjugated polymeric main chain;
- and
- a porphyrin compound having an absorption in a blue light region of solar radiation, and is bonded to the polymeric main chain to form a side chain on the polymeric main chain,
- wherein the porphyrin compound is a macro molecular heterocyclic compound and is one selected from a group consisting of P1, P2 and P3, wherein P1, P2 and P3 are shown as follows;
- M is one of Zn2+ and 2H+;
- G3 is π;
- each of S1 and S2 is one selected from a group consisting of a straight-chain saturated C1-30 alkyl group, a branched-chain saturated C1-30 alkyl group and an aryl group;
- and
- Z is one selected from a group consisting of Z1, Z2, Z3, Z4, Z5, Z6, Z7 and Z8, wherein Z1, Z2, Z3, Z4, Z5, Z6, Z7 and Z8 are shown as follows
A conjugated polymer compound, comprising a main chain and a side chain, wherein the side chain includes a porphyrin compound, and the conjugated polymer compound has the structure (A),
- n ranges from 1 to 100;
- R2 is a straight-chain saturated C8 alkyl group and R3 is a straight-chain saturated C10 alkyl group;
- each of S1 and S2 is one selected from a group consisting of straight-chain and branched-chain saturated C1-30 alkyl groups and an aryl group, and the aryl group has a phenyl group, wherein the phenyl group includes at least a substituent and the substituent is one selected from a group consisting of a hydrogen, a halogen, an alkyl halide, a cyano, a straight-chain saturated C1-30 alkyl group, a branched-chain saturated C1-30 alkyl group, a straight-chain saturated C1-30 alkoxy group, a branched-chain saturated C1-30 alkoxy group, a straight-chain saturated C1-30 alkylthio group, a branched-chain saturated C1-30 alkylthio group, a straight-chain saturated C1-30 ester group, a branched-chain saturated C1-30 ester group, a straight-chain saturated C1-30 acetyl group, and a branched-chain saturated C1-30 acetyl group, wherein each of S1 and S2 is 1,3-bis(dodecyloxy)benzene;
- and
- Z is one selected from a group consisting of Z1, Z2, Z3, Z4, Z5, Z6, Z7 and Z8, wherein Z1, Z2, Z3, Z4, Z5, Z6, Z7 and Z8 are shown as follows
Dependencies are inferred from the claim text.