Regeneration of an ionic liquid catalyst using metal complexes
AssigneeUop LLC
InventorsStuart Smith, Alakananda Bhattacharyya, Susie C. Martins
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Abstract
A method for regenerating deactivated ionic liquid catalyst containing conjunct polymer. The deactivated ionic liquid catalyst containing the conjunct polymer is contacted with either at least one metal complex having a general formula M1n+Rn, or at least one metal complex having a general formula [M2a+]x[M3b+yRz](xa/(z−by)). The conjunct polymer reacts with the reagent and can be extracted from the ionic liquid. The mixture is separated into a hydrocarbon effluent and an ionic liquid effluent.
Claims20
A method for regenerating deactivated ionic liquid catalyst containing conjunct polymer comprising:
- contacting the deactivated ionic liquid catalyst containing the conjunct polymer in a regeneration zone under regeneration conditions with either:
- at least one metal complex having a general formula M1n+Rn, where M1 is aluminum, gallium, zinc, magnesium, copper, iron, nickel, cobalt, chromium, boron, lithium, sodium, potassium, or calcium;
- R has a −1 charge and is independently selected from substituted and unsubstituted hydrocarbyl groups having 1-10 carbons, hydride, or halides, and n+ is the oxidation state of M1, the conjunct polymer reacting with the at least one metal complex having a general formula M1n+Rn, resulting in a reaction mixture comprising a first ionic liquid, at least one metal compound containing M1, and the conjunct polymer;
- or
- at least one metal complex having a general formula [M2a+]x[M3b+yRz](xa/(z−by)), where M2 is lithium, sodium, potassium, magnesium, or calcium, M3 is aluminum, gallium, zinc, copper, iron, nickel, cobalt, chromium or boron, R has a −1 charge and is independently selected from substituted and unsubstituted hydrocarbyl groups having 1-10 carbons, hydride, or halides, a+ is the oxidation state of M2, b+ is the oxidation state of M3, x is the number of M2 ions, y is the number of M3, and z is the number of R groups, the conjunct polymer reacting with the at least one metal complex having the general formula [M2a+]x[M3b+yRz](xa/(z−by)) resulting in a mixture comprising a second ionic liquid, at least one metal compound containing the M2 ion, a metal compound containing M3, and the conjunct polymer;
- and
- separating the mixture into a hydrocarbon effluent and an ionic liquid effluent, the hydrocarbon effluent comprising the conjunct polymer, and the ionic liquid effluent comprising:
- the first ionic liquid and the at least one metal compound containing M1;
- or the second ionic liquid, the at least one metal compound containing the M2 ion, and the metal compound containing M3.
Dependencies are inferred from the claim text.