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US 9,166,176 B2Granted
Polycyclic aromatic compound
AssigneesKyoto University, Jnc Corporation
InventorsTakuji Hatakeyama, Masaharu Nakamura, Sigma Hashimoto
Life of this patent
Estimating the term…
Abstract
The invention provides a polycyclic aromatic compound or a salt thereof having a partial structure represented by the following general formula (I): wherein X, ring A, ring B, ring C, and ring D are as defined in the specification.
Claims7
A polycyclic aromatic compound or a salt thereof represented by the following formula (I):
- wherein
- X represents B, P, P═O, P═S, P═Se, As, As═O, As═S, As═Se, Sb, Sb═O, Sb═S, Sb═Se, an optionally substituted metal in groups 3 to 11 in the periodic table, or an optionally substituted metal or metalloid in group 13 or 14 of the periodic table;
- and
- ring A, ring B, ring C, and ring D are the same or different, and each represents an optionally substituted phenyl ring, an optionally substituted phenyl ring fused to an aryl or heteroaryl ring, or an optionally substituted phenyl ring wherein a carbon atom of two adjacent rings are bonded to form a pyrrole ring,
- wherein the compound represented by formula (I) is not a fullerene or a heterofullerene.
2 more elements
A compound or a salt thereof represented by any one of the following formulas (III′-1) to (XIV′-1A):
- wherein
- X represents B, P, P═O, P═S, P═Se, As, As═O, As═S, As═Se, Sb, Sb═O, Sb═S, Sb═Se, an optionally substituted metal in groups 3 to 11 in the periodic table, or an optionally substituted metal or metalloid in group 13 or 14 of the periodic table;
- R represents a hydrogen atom, halogen atom, C1-20 alkyl group, hydroxy C1-20 alkyl group, trifluoromethyl group, C2-12 perfluoroalkyl group, C3-8 cycloalkyl group, C2-20 alkenyl group, C2-20 alkynyl group, mono- or di-aryl-substituted alkenyl group, mono- or di-heteroaryl-substituted alkenyl group, arylethynyl group, heteroarylethynyl group, hydroxy group, C1-20 alkoxy group, aryloxy group, trifluoromethoxy group, trifluoroethoxy group, C2-12 perfluoroalkoxy group, C1-20 alkylcarbonyl group, C1-20 alkylsulfonyl group, cyano group, nitro group, amino group, monoalkylamino group, monoarylamino group, monoheteroarylamino group, carbazole group, C1-20 alkoxycarbonylamino group, carbamoyl group, mono- or di-alkylcarbamoyl group, sulfamoyl group, mono- or di-alkylsulfamoyl group, C1-20 alkylsulfonylamino group, C1-20 alkylcarbonylamino group, aryl group, heteroaryl group, C1-20 alkoxycarbonyl group, carboxyl group, 5-tetrazolyl group, sulfo group (—SO2OH), fluorosulfonyl group, SRa, N(Ra)2, B(Ra)2, Si(Ra)3, or —C≡C—Si(Ra)3
- (wherein Ra represents an optionally substituted alkyl group, an optionally substituted aryl group, or an optionally substituted heteroaryl group;
- or two Ras, together with an atom bound thereto, may form a bicyclic group or a tricyclic group optionally having a heteroatom);
- provided that, the alkyl group, the alkenyl group, the alkynyl group, and the alkoxy group are each optionally substituted with 1 to 3 atoms or groups, selected from the group consisting of halogen atom, hydroxy group, C1-20 alkoxy group, aryloxy group, amino group, carbazole group, N(Ra)2 (wherein Ra is as defined above), trifluoromethyl group, C2-12 perfluoroalkyl group, C3-8 cycloalkyl group, aryl group, and heteroaryl group;
- and the aryl group, aryl moiety, heteroaryl group, heteroaryl moiety, and carbazole group are each optionally substituted with 1 to 5 atoms or groups, selected from the group consisting of halogen atom, C1-20 alkyl group, hydroxy C1-20 alkyl group, trifluoromethyl group, C2-12 perfluoroalkyl group, C3-8 cycloalkyl group, C2-20 alkenyl group, C2-20 alkynyl group, mono- or di-aryl-substituted alkenyl group, mono- or di-heteroaryl-substituted alkenyl group, arylethynyl group, heteroarylethynyl group, hydroxy group, C1-20 alkoxy group, aryloxy group, trifluoromethoxy group, trifluoroethoxy group, C2-12 perfluoroalkoxy group, cyano group, nitro group, amino group, carbazole group, monoalkylamino group, monoarylamino group, monoheteroarylamino group, N(Ra)2
- (wherein Ra is as defined above), carbamoyl group, mono- or di-alkylcarbamoyl group, sulfamoyl group, mono- or di-alkylsulfamoyl group, C1-20 alkylcarbonyl group, C1-20 alkylsulfonyl group, C1-20 alkylsulfonylamino group, C1-20 alkylcarbonylamino group, methylenedioxy group, heteroaryl group, and aryl group (wherein the aryl group is optionally substituted with 1 to 5 atoms or groups, selected from the group consisting of halogen atom, C1-20 alkyl group, C3-8 cycloalkyl group, C2-20 alkenyl group, C2-20 alkynyl group, hydroxy group, trifluoromethyl group, C2-12 perfluoroalkyl group, C1-20 alkoxy group, aryloxy group, trifluoromethoxy group, trifluoroethoxy group, C2-12 perfluoroalkoxy group, C1-20 alkylcarbonyl group, C1-20 alkylsulfonyl group, methylenedioxy group, cyano group, nitro group, amino group, carbazole group, and N(Ra)2 (wherein Ra is as defined above).
5 more elements
Dependencies are inferred from the claim text.