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US 9,126,163 B2Granted
Nanoemulsions and processes for their preparation, and their use as formulations of plant protection agents and/or pesticides and/or cosmetic preparations
AssigneeEvonik Degussa GmbH
InventorsSabine Giessler-Blank, Ralph Scheuermann, Joachim Venzmer, David Lindsay
Life of this patent
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Abstract
Nanoemulsions and processes for their preparation, and their use as formulations of plant protection products and/or pesticides and/or cosmetic preparations.
Claims21
A process for preparing a nanoemulsion comprising:
- providing or obtaining a microemulsion comprising:
- at least one pseudo-cosmotropic substance which is sparingly soluble in water or insoluble in water, and which lowers a temperature of at least one phase boundary of the microemulsion to a lower level as compared to the microemulsion without the at least one pseudo-cosmotropic substance;
- and
- at least one oil spreader as an adjuvant, wherein the oil spreader is an organo-modified polysiloxane of the general formula (1):
- where:
- z=independently of one another 0 or 1;
- x=0 to 200;
- y=0 to 100;
- R′=R or an alkyl radical;
- R=(CH2)n—(O)o—(C2H4O)p(C3H6O)q(C2H3LO)r—K and/or CmH2m+1;
- n=0, 3, 4 or 6;
- o=0 or 1;
- m=1 to 40;
- p=0 to 50;
- q=0 to 50;
- r=0 to 50;
- L=ethyl or phenyl;
- and
- K is H, an alkyl radical having 4 or fewer carbon atoms, or is an acetyl group;
- with the proviso that formula (1) must comprise at least one group R;
- and
- diluting the microemulsion with water in a ratio of 1:20 to 1:10,000, based on parts by weight, to obtain the nanoemulsion;
- wherein the nanoemulsion is storage stable and has an average particle size distribution in the range of from 10-200 nm for at least 48 hours at 40° C.;
- and
- wherein the at least one pseudo-cosmotropic substance includes at least one substance selected from the group consisting of pesticidal actives.
22 more elements
Dependencies are inferred from the claim text.