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US 9,115,157 B2Granted
Regulator molecule
AssigneeSika Technology AG
InventorsUeli Sulser, Lukas Frunz, Jörg Zimmermann
Life of this patent
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Abstract
The invention relates to a mono-substituted phosphinic acid and to the use thereof as a regulator in radical polymerization. Such regulators do not result in the formation of poorly soluble salts, and in addition, the polymers produced with the regulators according to the invention are characterized by a uniform polymerization degree having a narrow size distribution. In addition, the invention relates to a method for producing such mono-substituted phosphinic acids.
Claims16
Mono-substituted phosphinic acid of formula (I)
- wherein X is H+, an alkali metal ion, alkaline earth metal ion, divalent or trivalent metal ion, ammonium ion, organic ammonium group or an organic radical with a molecular weight of ≦200 g/mol;
- wherein Y represents one of the formulas (II) to (VI)
- where (P) and (W) correspond to P and W, respectively, in formula (I),
- wherein W represents one of the formulas (VII) to (X);
- where (Y) and (R1) correspond to Y and R1, respectively, in formula (I),
- wherein R1 is H, an alkyl group, an alkylaryl group, or the formula (XI)
- wherein the substituent A independently represents a C2- to C4-alkylene group, the subscript q has a value of 2 to 300, the subscript n represents a value of 2 to 4, and the subscript r represents a value of 0 to 1,
- wherein R2, R3 and R4 independently represent H, CH3, COOH or CH2—COOH,
- R5 is —CH2—CH2— or —CH2—CH(CH3) and
- R6 is O or N.
7 more elements
Dependencies are inferred from the claim text.