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US 9,109,176 B2Granted
Method for making marine bunker fuels
AssigneeExxonMobil Research and Engineering Company
InventorsDavid L. Stern, Salvatore R. Di Mauro, Aldo Roccaro, Paul W. Bessonette
Life of this patent
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Abstract
This invention relates to low sulfur marine/bunker fuel compositions and methods of making same. Contrary to conventional marine/bunker fuel compositions/methods, the inventive lower sulfur compositions/methods focus on use of mostly uncracked components, such as (cat feed) hydrotreated gasoils, and/or can also have reduced contents of residual components.
Claims12
A method for making a low sulfur marine bunker fuel composition with a reduced concentration of components that have been cracked, the method comprising:
- producing an uncracked gasoil product by contacting a gasoil feed stream having at least 2000 wppm sulfur content with a hydrogen-containing gas in the presence of a hydrotreating catalyst under effective hydrotreating conditions in a catalytic feed hydrotreater, such that the product exhibits at most 5000 wppm sulfur content, a T5 boiling point of at least 280° C., a T50 boiling point of at least 400° C., a T95 boiling point of at least 510° C., a pour point of at least 7° C., and a kinematic viscosity of at least 12 cSt at about 50° C., without the product being subject to cracking;
- optionally blending at least a portion of the uncracked gasoil product with 0-70 vol % of other components, selected from viscosity modifiers, pour point depressants, lubricity modifiers, antioxidants, and combinations thereof, to form a marine bunker fuel composition containing the uncracked gasoil product and having:
- at most 5000 wppm sulfur content;
- at most 25 vol %, based on all components of the marine bunker fuel composition, of residual components selected from crude fractionation vacuum resid, deasphalted vacuum resid, slurry oil, and combinations thereof;
- less than 50 vol %, based on all components of the marine bunker fuel composition, of residual components, components subject to a refinery cracking step, or both;
- and
- at least one of a kinematic viscosity at about 50° C. from 12 cSt to 50 cSt, a density at about 15° C. from 0.90 g/cm3 to 0.94 g/cm3, a pour point from 7° C. to 45° C., and a calculated carbon aromaticity index of 850 or less.
4 more elements
Dependencies are inferred from the claim text.