Process of producing xylose and dissolving pulp
AssigneeDupont Nutrition Biosciences Aps
InventorsHeikki Heikkila, Jari Lewandowski, Mirja Lindroos, Pia Saari
Life of this patent
Estimating the term…
Abstract
The present invention relates to a process for the production of xylose and dissolving pulp from xylan-containing biomass, such as hardwood. The invention is based on prehydrolysis of the xylan-containing biomass with SO2 in specified conditions, followed by chromatographic fractionation, nanofiltration or precipitation crystallization of the xylose-containing prehydrolyzate to obtain a xylose product having a xylose content of at least 55% on DS. The dissolving pulp obtained from the process can be used for example for the production of viscose.
Claims31
A process for the production of xylose and dissolving pulp from a hardwood biomass, which has a xylan content of 10 to 35%, calculated on the dry substance (DS) of the biomass,
- comprising the steps of:
- (a) prehydrolyzing the hardwood biomass in a digester with a solution containing sulphur dioxide in a concentration of 0.1 to 2.5% based on the total liquid weight of the prehydrolysis liquid, at a temperature of 120-150° C., a liquid-to-biomass ratio of less than 6, and with a reaction time of 0.3 to 1 h, to provide (1) a dissolved hemicellulose hydrolyzate, wherein the xylose content is 25 to 55% of the dissolved solids of the hydrolyzate, the ratio of xylose to xylo-oligomers is more than 2 and the xylose yield is 30 to 80% on xylan in the biomass, and (2) a non-dissolved prehydrolyzed biomass,
- (b) separating the dissolved hemicellulose hydrolyzate from the non-dissolved prehydrolyzed biomass,
- (c) subjecting the dissolved hemicellulose hydrolyzate to chromatographic fractionation, nanofiltration or precipitation crystallization to obtain a xylose product having a xylose content of at least 55% on DS, and
- (d) subjecting the non-dissolved prehydrolyzed biomass to sulphate cooking in a digester to obtain a dissolving pulp with a viscosity of more than 600 ml/g.
Dependencies are inferred from the claim text.