Method for producing ternesite-belite calcium sulfoaluminate clinker
AssigneeHeidelbergcement AG
InventorsFrank Bullerjahn, Dirk Schmitt, Mohsen Ben Haha
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Abstract
The present invention relates to the production of a ternesite-belite-calcium sulfoaluminate (ferrite) clinker. The invention also relates to the use of alternative raw materials for clinker production, for example raw materials based on industrial byproducts, including those of low quality, such as lump slag and ash having a low glass content and/or a high free lime content and/or a high content of crystalline high-temperature phases, as well as naturally occurring rocks and rock glasses of comparative chemical composition.
Claims29
A method for producing a hydraulically reactive clinker by sintering a raw meal mixture, which contains sources for CaO, Al2O3(Fe2O3), SiO2 and SO3, wherein
- the raw meal mixture is sintered in a temperature range of >1200° C. to 1350° C. over a period of time sufficient to convert the raw meal mixture into a clinker intermediate product,
- the clinker intermediate product is tempered in a temperature range of 1200° C. to a lower limit of 750° C. over a period of time sufficient to obtain 5 to 75 wt % of C5S2$ and to convert an amount of aluminate and ferrate phases and residues of crystalline high-temperature phases of the raw meal mixture with remaining C$ into additional C4(AxF1-x)3$ and C5S2$, and
- the clinker comprising main components C4(AxF1-x)3$, (α;
- β) C2S, and C5S2$ in the following proportions
- C5S2$
- 5 to 75 wt %
- C2S
- 1 to 80 wt %
- C4(AxF1−x)3$
- 5 to 70 wt %
- one or more
- 0 to 30 wt %,
- secondary phases
- wherein x is a number from 0.1 to 1, is cooled.
Dependencies are inferred from the claim text.