Microporous material having degradation properties and articles prepared therefrom
AssigneePPG Industries Ohio, Inc.
InventorsChristine Gardner, James L. Boyer
Life of this patent
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Abstract
The present invention is directed to biodegradable microporous materials and multi-layer articles containing them. The biodegradable microporous materials comprise: (a) a polyolefin matrix, (b) finely divided, particulate filler distributed throughout the matrix, (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material, and (d) a biodegradation promoting material distributed throughout the matrix. Also provided are multilayer articles prepared from the above-described microporous materials.
Claims26
A biodegradable microporous material comprising:
- (a) a polyolefin matrix,
- (b) finely divided, substantially water-insoluble particulate filler distributed throughout the polyolefin matrix, said filler constituting from 30 to 90 weight percent of the microporous material,
- (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material, and
- (d) an amount of biodegradation promoting material distributed throughout the polyolefin matrix that is sufficient to render the microporous material biodegradable, said biodegradation promoting material comprising a furanone compound, a glutatic acid, a hexadecanoic acid compound, an organoleptic swelling agent or mixtures thereof.
A biodegradable multilayer article comprising:
- (a) at least one layer of a microporous material and
- (b) at least one layer of a material that is the same as or different from the microporous material (a), wherein the microporous material comprises:
- (i) a polyolefin matrix,
- (ii) finely divided, substantially water-insoluble particulate filler distributed throughout the polyolefin matrix, said filler constituting from 30 to 90 weight percent of the microporous material,
- (iii) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material, and
- (iv) an amount of biodegradation promoting material distributed throughout the polyolefin matrix that is sufficient to render the microporous material biodegradable, said biodegradation promoting material comprising a furanone compound, a glutaric acid, a hexadecanoic acid compound, an organoleptic swelling agent or mixtures thereof.
A biodegradable microporous material comprising:
- (a) a polyolefin matrix,
- (b) from 50 to 85 weight percent of substantially water-insoluble finely divided, particulate filler distributed throughout the polyolefin matrix,
- (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material, and
- (d) an amount of biodegradation promoting material distributed throughout the polyolefin matrix that is sufficient to render the microporous material biodegradable, said biodegradation promoting material comprising a furanone compound, a glutaric acid, a hexadecanoic acid compound, an organoleptic swelling agent or mixtures thereof.
A biodegradable microporous material comprising:
- (a) a polyolefin matrix comprising a mixture of (i) ultrahigh molecular weight polyethylene having an intrinsic viscosity of from 18 to 32 deciliters/gram and (ii) lower molecular weight polyethylene having an ASTM D 1238-86 Condition E melt index of less than 50 grams/10 minutes and an ASTM D 1238-86 Condition F melt index of at least 0.1 gram/10 minutes,
- (b) from 50 to 85 weight percent, based on the microporous material, of finely divided, particulate substantially water-insoluble filler distributed throughout the polyolefin matrix,
- (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material, and
- (d) an amount of a biodegradation promoting material distributed throughout the polyolefin matrix that is sufficient to render the microporous material biodegradable, said biodegradation promoting material comprising a furanone compound, a glutaric acid, a hexadecanoic acid compound, an organoleptic swelling agent or mixtures thereof.
A biodegradable microporous material comprising:
- (a) a polyolefin matrix comprising a mixture of (i) ultrahigh molecular weight polyethylene having an intrinsic viscosity of from 18 to 39 deciliters/gram and (ii) lower molecular weight polyethylene having an ASTM D 1238-86 Condition E melt index of less than 25 grams/10 minutes and an ASTM D 1238-86 Condition F melt index of at least 0.5 gram/10 minutes,
- (b) from 50 to 85 weight percent, based on the microporous material, of finely divided, particulate substantially water-insoluble filler distributed throughout the polyolefin matrix,
- (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material, and
- (d) biodegradation promoting material distributed throughout the polyolefin matrix, said biodegradation promoting material comprising a furanone compound, a glutaric acid, a hexadecanoic acid compound, an organoleptic swelling agent, or mixtures thereof.
Dependencies are inferred from the claim text.