Handling of acids from compressed oxyfuel-derived CO2

Apparatus for removing SO2 from a carbon dioxide feed gas comprising SO2 as a contaminant, said apparatus comprising:

• a first compression system for compressing carbon dioxide feed gas, or SO2-lean carbon dioxide gas derived therefrom, to produce carbon dioxide gas feed at a first elevated pressure;
• a first column for washing the carbon dioxide gas feed with water at the first elevated pressure to produce intermediate SO2-depleted carbon dioxide gas and a first acid condensate mixture of sulfuric acid condensate and nitric acid condensate;
• a conduit arrangement for feeding the carbon dioxide gas feed from the first compression system to the first column;
• an acid/sorbent reactor system for operation at the first elevated pressure;
• a conduit arrangement for feeding the first acid condensate mixture from the first column to the acid/sorbent reactor system;
• a second compression system for compressing the intermediate SO2-depleted carbon dioxide gas to a second elevated pressure that is higher than the first elevated pressure;
• a conduit arrangement for feeding the intermediate SO2-depleted carbon dioxide gas from the first column to the second compression system;
• a second column for washing the intermediate SO2-depleted carbon dioxide gas with water at the second elevated pressure to produce SO2-depleted, NOx-lean carbon dioxide gas and a second acid condensate mixture of sulfuric acid condensate and nitric acid condensate, said second column having an outlet for removing second acid condensate;
• a conduit arrangement for feeding the intermediate SO2-depleted carbon dioxide gas from the second compression system to the second column;
• a conduit arrangement for removing the SO2-depleted, NOx-lean carbon dioxide gas from the second column;
• a depressurization system for depressurizing the second acid condensate mixture to produce reduced pressure second acid condensate mixture and desorbed carbon dioxide gas at the first elevated pressure;
• a conduit arrangement for feeding the second acid condensate mixture from the second column to the depressurization system;
• a conduit arrangement for feeding the reduced pressure second acid condensate mixture and desorbed carbon dioxide gas to the acid/sorbent reactor system;
• and
• a conduit arrangement for recycling recovered carbon dioxide gas from the acid/sorbent reactor system to the first column or the second compression system.

Apparatus for removing SO2 from a carbon dioxide feed gas comprising SO2 as a contaminant, said apparatus comprising:

• a sour gas reactor system for maintaining said carbon dioxide feed gas, or a SO2-lean carbon dioxide gas derived therefrom, at elevated pressure(s) in the presence of O2, water and NOx for a period of time sufficient to convert SO2 to sulfuric acid condensate and NOx to nitric acid condensate, said sour gas reactor system comprising at least one stage operable at elevated pressure;
• a first separation system for separating said acid condensates from said carbon dioxide gas to produce SO2-depleted, NOx-lean carbon dioxide gas;
• an acid/sorbent reactor system for neutralizing at least a portion of said acid condensates by reaction with an alkaline sorbent to produce sorbent-derived sulfate and sorbent-derived nitrate, said acid/sorbent reactor system being operable at a lower pressure than said elevated pressure, said lower pressure being at least 2 bar;
• a conduit arrangement for feeding said acid condensates from said first separation system to said acid/sorbent reactor system, said conduit arrangement comprising a depressurization system for depressurizing said acid condensates produced at said stage of said sour gas reactor system to produce reduced pressure acid condensates and desorbed carbon dioxide gas at said lower pressure, prior to feeding said acid condensates to said acid/sorbent reactor system;
• a conduit arrangement for feeding said acid condensates from said first separation system to said depressurization system;
• a second separation system for separating said reduced pressure acid condensates from said desorbed carbon dioxide gas;
• a conduit arrangement for feeding said reduced pressure acid condensates and desorbed carbon dioxide gas from said depressurization system to said second separation system;
• and
• a conduit arrangement for feeding said reduced pressure acid condensates from said second separation system to said acid/sorbent reactor system.