Organic electronic device

An organic electronic device comprising at least one oligomer, polymer or dendrimer which comprises one or more compounds of the formulae (1) to (6)

• where the following applies to the symbols and indices used:
• X is on each occurrence, identically or differently, CR1 or N;
• Y is on each occurrence, identically or differently, a divalent group selected from the group consisting of B(R1)2, C(R1)2, NR1, O, S, C(═O), C═C(R1)2, S(═O), S(═O)2, P(═O)(R1)2, and a divalent aromatic or heteroaromatic ring system having 5 to 18 aromatic ring atoms, which is optionally substituted by one or more radicals R1;
• R is on each occurrence, identically or differently, H, D, F, Cl, Br, I, CHO, N(R1)2, N(Ar)2, C(═O)Ar, P(═O)(Ar)2, S(˜0)Ar, S(═O)2Ar, CR1═CR1Ar, CN, NO2, Si(R1)3, B(OR1)2, B(R1)2, B(Ar)2, B(N(R1)2)2, OSO2R1, a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 40 C atoms or a straight-chain alkenyl or alkynyl group having 2 to 40 C atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 C atoms, each of which is optionally substituted by one or more radicals R1, where one or more non-adjacent CH2 groups is optionally replaced by R1C═CR1, Si(R1)2, Ge(R1)2, Sn(R1)2, C═O, C═S, C═Se, C═NR1, P(═O)(R1), SO, SO2, NR1, O, S or CONR1 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I, CN or NO2, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R1, or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R1, or a combination of these systems;
• R1 is on each occurrence, identically or differently, H, D, F, Cl, Br, I, CHO, N(R2)2, N(Ar)2, C(═O)Ar, P(═O)(Ar)2, S(═O)Ar, S(═O)2Ar, CR2═CR2Ar, CN, NO2, Si(R2)3, B(OR2)2, B(R2)2, B(N(R2)2)2, OSO2R2, a straight-chain alkyl, alkoxy or thioalkoxy group having 1 to 40 C atoms or a straight-chain alkenyl or alkynyl group having 2 to 40 C atoms or a branched or cyclic alkyl, alkenyl, alkynyl, alkoxy or thioalkoxy group having 3 to 40 C atoms, each of which is optionally substituted by one or more radicals R2, where one or more non-adjacent CH2 groups is optionally replaced by R2C═CR2, Si(R2)2, Ge(R2)2, Sn(R2)2, C═O, C═S, C═Se, C═NR2, P(═O)(R2), SO, SO2, NR2, O, S or CONR2 and where one or more H atoms is optionally replaced by D, F, Cl, Br, I, CN or NO2, or an aromatic or heteroaromatic ring system having 5 to 60 aromatic ring atoms, which may in each case be substituted by one or more radicals R2, or an aryloxy or heteroaryloxy group having 5 to 60 aromatic ring atoms, which may be substituted by one or more radicals R2, or a combination of these systems;
• Ar is on each occurrence, identically or differently, an aromatic or heteroaromatic ring system having 5 to 30 aromatic ring atoms, which is optionally substituted by one or more non-aromatic radicals R1;
• two radicals Ar which are bonded to the same nitrogen or phosphorus atom which is optionally linked to one another here by a single bond or a bridge selected from B(R2), C(R2)2, Si(R2)2, C═O, C═NR2, C═C(R2)2, O, S, S═O, SO2, N(R2), P(R2) and P(═O)R2;
• R2 is on each occurrence, identically or differently, H, D or an aliphatic, aromatic and/or heteroaromatic hydrocarbon radical having 1 to 20 C atoms, in which, in addition, H atoms is optionally replaced by F;
• two or more adjacent substituents R2 here optionally form a mono- or polycyclic, aliphatic or aromatic ring system with one another;
• n is 0, 1, 2, 3, 4, 5 or 6;
• m is 0, 1, 2 or 3;
• p is on each occurrence, identically or differently, 0, 1, 2 or 3, where one or more radicals R represent bonds from the compound of the formulae (1) to (6) to the polymer, oligomer or dendrimer wherein the compounds of the formulae (1) to (6) are employed as electron-transport material or as hole-blocking material in an electron-transport layer or hole-blocking layer or as charge-generation material in a charge-generation layer, and
• wherein the organic electronic device is selected from the group consisting of organic electroluminescent devices (OLEDs), organic integrated circuits (G-ICs), organic field-effect transistors (O-FETs), organic thin-film transistors (O-TFTs), organic light-emitting transistors (O-LETs), organic solar cells (O-SCs), organic optical detectors, organic photoreceptors, organic field-quench devices (O-FQDs), light-emitting electrochemical cells (LECs) and organic laser diodes (O-lasers).