Active energy ray-curable resin composition, and production method for products with surfaces of fine concave-convex structures

A mass production method for producing a product having a cured resin layer with a fine concave-convex structure formed on a surface of a substrate using the same mold, the method comprising

• (i) filling a space between a mold having a fine concave-convex structure composed of anodized alumina on a surface thereof and a substrate with an active energy ray-curable resin composition,
• (ii) curing the composition by irradiation with active energy rays, thereby forming a cured resin layer into which the fine concave-convex structure has been transferred on a surface of the substrate,
• (iii) recovering the product having a cured resin layer with a fine concave-convex structure formed on a surface of the substrate, and
• repeating steps (i), (ii) and (iii) in sequence using the same mold to produce corresponding numbers of the product having a cured resin layer with a fine concave-convex structure formed on a surface of the substrate, wherein
• (A) the method comprises treating a surface of the mold with a fluorine compound, at Least at transfer initiation,
• (B) the active energy ray-curable resin composition comprises a polymerizable Compound, a polymerization initiator, and a (poly)oxyethylene alkyl phosphate ester compound, And
• an average spacing between convex protrusions or concave recesses of the fine concave-convex Structure is not more than 400 nm.

A mass production method for producing a product having a cured resin layer with a fine concave-convex structure formed on a surface of a substrate using a rotating roll-shaped mold having a fine concave-convex structure composed of anodized alumina on a surface thereof in which the convex protrusions or concave recesses have an average spacing therebetween of not more than 400 nm, the method comprising, while rotating the roll-shaped mold,

• (i) feeding a belt-shaped substrate to the roll-shaped mold provided the surface of the substrate is spaced apart from the opposing surface of the rotating mold when conducting the feeding so as to receive an active energy ray-curable resin composition therebetween;
• (ii) introducing an active energy ray-curable resin composition into the space between the rotating mold and the belt-shaped substrate when conducting the feeding to form a curable resin layer into which the fine concave-convex structure is transferred, the active energy ray-curable resin composition comprising a polymerizable compound, a polymerization initiator, and a (poly)oxyethylene alkyl phosphate ester compound;
• (iii) forming the cured resin layer into which the fine concave-convex structure has been transferred on the surface of the belt-shaped substrate by irradiating the curable resin layer active energy ray-curable composition with active energy rays;
• and
• (iv) peeling the product from the surface of the rotating roll-shaped mold, the product comprising the cured resin layer having the fine concave-convex structure formed on the surface of the belt-shaped substrate,
• wherein the method includes
• (v) treating a surface of the mold with a fluorine compound, at least at transfer initiation.