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US 9,048,480 B2Granted
Anion exchange polymer electrolytes
AssigneeLos Alamos National Security, LLC
InventorsYu Seung Kim, Dae Sik Kim
Life of this patent
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Abstract
Anion exchange polymer electrolytes that include guanidinium functionalized polymers may be used as membranes and binders for electrocatalysts in preparation of anodes for electrochemical cells such as solid alkaline fuel cells.
Claims8
A composition having the formula
- wherein X is S or O;
- wherein Y is
- wherein Z is SO2 or S,
- wherein n is from 1 to 1000, and
- wherein G comprises guanidine or guanidinium, said guanidine having the formula
- said guanidinium having the formula
- wherein R1, R2, R3, and R4 are each independently selected from —H, —CH3, —NH2, —N(═O), —NO2, —CN, —(CH)mCH3 wherein m=1-6, HC(═O)—, CH3C(═O)—, NH2C(═O)—, —(CH2)mCOOH where m=1-6, —(CH2)mCH(NH2)—COOH where m=1-6, —CH—(COOH)—CH2—COOH, —CH2—CH(O—CH2CH3)2, —(C═S)—NH2, —(C═NH)—N((CH2)n1(CH3)((CH2)n2(CH3)) where n1=0-6 and n2=0-6, —NH—(C═S)—SH, —CH2—C(═O)—O—C(CH3)3, —O—(CH2)m—CH(NH2)—COOH, where m=1-6, —(CH2)m—CH═CH2 wherein m=1-6, —(CH2)m—CH2—CN where m=1-6, an aromatic group, a halide, or halide-substituted methyl group,
- wherein R5=alkyl, and
- wherein A− is a counterion.
6 more elements
Dependencies are inferred from the claim text.