# US 9,040,207 B2 · Method for operating a high-temperature fuel cell

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- Number: US 9,040,207 B2
- Document ID: US9040207B2
- Status: Granted
- Kind: B2
- Application number: 13/375,371
- Filed: 2010-07-15
- Published: 2012-04-26
- Granted: 2015-05-26
- Earliest claimed: 2009-07-16
- Assignees: AVL List GmbH
- Applicants: Peter Prenninger; Juergen Rechberger
- Inventors: Peter Prenninger; Juergen Rechberger
- Web page: https://patentgrep.com/patent/US9040207B2

## CPC

- H01M 8/04097: {with recycling of the reactants (H01M8/04119, H01M8/04104 take precedence)}
- H01M 8/04231: {Purging of the reactants}
- H01M 8/0618: {Reforming processes, e.g. autothermal, partial oxidation or steam reforming}
- H01M 8/04111: using a compressor turbine assembly
- H01M 2008/1293: {Fuel cells with solid oxide electrolytes}
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

In a method for operating a high-temperature fuel cell, which in normal mode of generating electrical power is supplied with liquid fuel, preferably diesel oil, and is preceded on the anode side by a reformer for liquid fuel, where at least part of the hot anode exhaust gas is recirculated into the anode circuit via a recirculation line. Upstream of a compressor preceding the reformer the liquid fuel is sprayed or injected into the hot anode exhaust gas, the quantity of air needed for reforming the liquid fuel being added to the mixture of anode exhaust gas and fuel. On change-over from normal operational mode to standby mode without power generation, the supply of liquid fuel and air is stopped and the gas mixture present in the anode circuit be permanently circulated. A defined amount of air being introduced into the anode circuit in order to remove deposits and contaminations in the high-temperature fuel cell following standby operation.

## Claims

### Claim 1

A method for operating a high-temperature fuel cell, which in normal operation mode of generating electrical power is supplied with liquid fuel, and is preceded on an anode side by a reformer for the liquid fuel, where at least part of hot anode exhaust gas of the fuel cell is recirculated into an anode circuit via a recirculation line, and where upstream of a compressor preceding the reformer the liquid fuel is sprayed or injected into the hot anode exhaust gas, a quantity of air needed for reforming the liquid fuel being added to the mixture of anode exhaust gas and fuel, wherein on change-over from normal operation mode to standby operation mode without power generation the supply of liquid fuel and air is stopped and the gas mixture present in the anode circuit is permanently circulated, and that—following standby operation mode—a defined amount of air is introduced into the anode circuit for removing deposits and contaminations in the high-temperature fuel cell.

### Claim 2 (depends on 1)

The method according to claim 1, wherein the introduced amount of air is determined such that an oxygen content of 0.5 to 10 volume percent is established in the anode circuit after oxidation of fuel components left in the anode circuit.

### Claim 3 (depends on 1)

The method according to claim 1, wherein the liquid fuel is diesel oil.

### Claim 4 (depends on 1)

The method according to claim 1, wherein an exhaust gas recirculation rate of up to 100% is set during standby operation mode,

### Claim 5 (depends on 1)

The method according to claim 1, wherein an exhaust gas recirculation rate of up to 100% is set during shut-down of the fuel cell.

### Claim 6 (depends on 1)

The method according to claim 1, wherein the anode circuit is closed on the outlet side during standby operation mode in order to avoid sucking in of ambient air.

### Claim 7

A method for operating a high-temperature fuel cell, which in normal operation mode of generating electrical power is supplied with liquid fuel, and is preceded on an anode side by a reformer for the liquid fuel, where at least part of hot anode exhaust gas of the fuel cell is recirculated into an anode circuit via a recirculation line, and where upstream of a compressor preceding the reformer the liquid fuel is sprayed or injected into the hot anode exhaust gas, a quantity of air needed for reforming the liquid fuel being added to the mixture of anode exhaust gas and fuel, wherein on change-over from normal operation mode to standby operation mode without power generation the supply of liquid fuel and air is stopped and the gas mixture present in the anode circuit is permanently circulated, and that—following standby operation mode—the recirculation line for the anode exhaust gas is closed and air is directly supplied to the anode circuit upstream of the reformer for removing deposits and contaminations in the high-temperature fuel cell.

### Claim 8 (depends on 7)

The method according to claim 7, wherein the liquid fuel is diesel oil.

### Claim 9 (depends on 7)

The method according to claim 7, wherein an exhaust gas recirculation rate of up to 100% is set during standby operation mode.

### Claim 10 (depends on 7)

The method according to claim 7, wherein an exhaust gas recirculation rate of up to 100% is set during shut-down of the fuel cell.

### Claim 11 (depends on 7)

The method according to claim 7, wherein the anode circuit is closed on the outlet side during standby operation mode in order to avoid sucking in of ambient air.