# US 9,040,142 B2 · Composite article comprising particles and a method of forming a composite article

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 9,040,142 B2
- Document ID: US9040142B2
- Status: Granted
- Kind: B2
- Application number: 13/697,593
- Filed: 2010-05-11
- Published: 2013-05-23
- Granted: 2015-05-26
- Earliest claimed: 2010-05-11
- Assignees: Saab AB
- Applicants: Björn Weidmann; Mikael Petersson; Per Hallander; Pontus Nordin; Tommy Grankäll
- Inventors: Björn Weidmann; Mikael Petersson; Per Hallander; Pontus Nordin; Tommy Grankäll
- Web page: https://patentgrep.com/patent/US9040142B2

## CPC

- B32B 5/12: characterised by the relative arrangement of fibres or filaments of {different layers, e.g. the fibres or filaments being parallel or perpendicular to each other}
- B29C 70/025: {with particular filler}
- B29C 70/202: {arranged in parallel planes or structures of fibres crossing at substantial angles, e.g. cross-moulding compound [XMC] (B29C70/207 takes precedence)}
- B29C 70/342: {using isostatic pressure}
- B29K 2105/243: {Partially cured}
- Y02T 50/40: Weight reduction
- Y10T 428/24124: Fibers
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

A composite article having a longitudinal direction and a transversal direction. The article includes a stack of plies wherein one ply is a bottom ply and one ply is a top ply. Most or all of the plies include fibers. A plurality of plies have fibers substantially in an orthogonal direction and substantially in a same direction as the longitudinally direction of the article. The bottom ply and the top ply have fibers in a substantially orthogonal direction to the longitudinal direction of the article. At least one ply has the fibers substantially in the same direction as the longitudinal direction of the article. At least one of the plies having fibers substantially in the longitudinal direction includes particles selected from the group of thermoplastic tougheners, nano particles, micro particles, elastic particles, elastomer particles and polymer particles or a combination. Also a method of forming an article on a tool.

## Claims

### Claim 1

A composite article having a longitudinal direction and a transversal transverse direction, the article comprising:
a stack of plies wherein one ply is a bottom ply and one ply is a top ply, most of the plies comprise fibers,
a plurality of plies having fibers substantially in a direction orthogonal to the longitudinal direction of the article and plies having fibers substantially in a same direction as the longitudinal direction of the article, wherein a bottom ply and a top ply have fibers substantially in the orthogonal direction to the longitudinal direction of the article, at least one ply has the fibers substantially in a same direction as the longitudinal direction of the article, and
at least one ply having fibers substantially diagonal to the longitudinal direction of the article, wherein the at least one ply having fibers substantially diagonal to the longitudinal direction of the article is arranged next to another ply having fibers substantially diagonal to the longitudinal direction of the article or between plies having fibers substantially orthogonal to the longitudinal direction of the article, wherein at least one of the at least one ply having fibers substantially in the longitudinal direction of the article and at least one of the at least one ply having the fibers substantially diagonal to the longitudinal direction of the article comprise particles, the particles including at least one member selected from the group of thermoplastic tougheners, nano particles, micro particles, elastic particles, elastomer particles and polymer particles, wherein the particles comprise carbon, ceramic material, organic material, or glass, and wherein at least one or more of the plies do not include particles.

### Claim 2 (depends on 1)

The composite article according to claim 1, wherein the article includes a thicker region or a build-up area, wherein the article comprises at least one ply which covers only the area of the thicker region or the build-up area.

### Claim 3 (depends on 1)

The composite article according to claim 1, wherein the article includes at least one curved part.

### Claim 4 (depends on 3)

The composite article according to claim 3, wherein the particles are placed in the region of the curved part.

### Claim 5 (depends on 1)

The composite article according to claim 1, wherein the article comprises a stack, wherein a bottom ply has fibers substantially orthogonal to the longitudinal direction of the article, a next four plies have fibers substantially diagonal to the longitudinal direction of the article, a next ply has fibers substantially orthogonal to the longitudinal direction of the article, a next four plies have fibers in substantially a same direction as the longitudinal direction of the article, a next ply has fibers substantially orthogonal to the longitudinal direction of the article, a four next plies have fibers substantially diagonal to the longitudinal direction of the article, the next ply has the fibers substantially orthogonal to the longitudinal direction of the article.

### Claim 6 (depends on 5)

The composite article according to claim 5, wherein the nano particles are selected from the group of nano tubes, nano double wall tubes, nano multi wall tubes, nano fibers, nano double wall fibers, nano filaments, nano double wall filaments and nano wires or a combination of them and the micro particles are selected from the group of micro tubes, micro double wall tubes, micro multi wall tubes, micro fibers, micro double wall fibers, micro filaments, micro double wall filaments and micro wires or a combination of them.

### Claim 7 (depends on 1)

The composite article according to claim 1, wherein at least one ply having fibers substantially in the orthogonal direction does not comprise particles.

### Claim 8 (depends on 1)

The composite article according to claim 1, wherein at least one ply having fibers substantially in the orthogonal direction comprises particles.

### Claim 9

A method of forming an article on a tool, the tool having one longitudinal direction L and one transverse direction T, the method comprising:
arranging a stack of plies, wherein most of or all of the plies comprise fibers, wherein the stack comprises a plurality of plies having fibers substantially in a direction orthogonal to the longitudinal direction of the tool and plies having fibers substantially in a same direction as the longitudinal direction of the tool, so that when positioned on the tool the ply arranged closest to the tool and the ply arranged furthest away from the tool have the fibers substantially in the orthogonal direction to the longitudinal direction of the tool, and arranging at least one ply having the fibers substantially in the same direction as the longitudinal direction of the tool between plies having fibers substantially orthogonal to the longitudinal direction of the tool,
arranging at least one ply having fibers substantially diagonal to the longitudinal direction of the tool, wherein the at least one ply having fibers substantially diagonal to the longitudinal direction of the tool is arranged next to another ply having fibers substantially diagonal to the longitudinal direction of the tool or between plies having fibers substantially orthogonal to the longitudinal direction of the tool, wherein at least one of the at least one ply having fibers substantially in the longitudinal direction of the tool and at least one of the at least one ply having the fibers substantially diagonal to the longitudinal direction of the tool comprise particles, the particles including at least one member selected from the group of thermoplastic tougheners, nano particles, micro particles, elastic particles, elastomer particles and polymer particles, wherein the particles comprise carbon, ceramic material, organic material, or glass, and wherein at least one or more of the plies do not include particles,
conforming the stack to the tool with a forming medium; and
removing the article from the tool.

### Claim 10 (depends on 9)

The method according to claim 9, wherein the tool has at least one depressed part and at least one protruding part, which protruding part is protruding in relation to the depressed part of the tool.

### Claim 11 (depends on 10)

The method according to claim 10, wherein the plies are arranged so that at least one of the plies covers at least a part of the at least one depressed part and not the at least one protruding part and the other plies cover both the at least one depressed parts and the at least one protruding parts.

### Claim 12 (depends on 9)

The method according to claim 9, further comprising:
arranging the stack so that when positioned on the tool a ply arranged closest to the tool has fibers substantially orthogonal to the longitudinal direction of the tool, a next four plies have fibers substantially diagonal to the longitudinal direction of the tool, a next ply has fibers substantially orthogonal to the longitudinal direction of the tool, a next four plies have fibers in substantially the same direction as the longitudinal direction of the tool, a next ply has the fibers substantially orthogonal to the longitudinal direction of the tool, a four next plies have fibers substantially diagonal to the longitudinal direction of the tool, and a next ply has fibers substantially orthogonal to the longitudinal direction of the tool.

### Claim 13 (depends on 9)

The method according to claim 9, wherein the tool comprises at least one curved part.

### Claim 14 (depends on 13)

The method according to claim 13, wherein the plies comprising particles are arranged so that the particles are placed in the area of the curved part.

### Claim 15 (depends on 9)

The method according to claim 9, wherein the nano particles are selected from the group of nano tubes, nano double wall tubes, nano multi wall tubes, nano fibres, nano double wall fibres, nano filaments, nano double wall filaments and nano wires or a combination of them and the micro particles are selected from the group of micro tubes, micro double wall tubes, micro multi wall tubes, micro fibres, micro double wall fibres, micro filaments, micro double wall filaments and micro wires or a combination of them.