# US 9,039,806 B2 · Recycling of solids in oxidative pressure leaching of metals using halide ions

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- Number: US 9,039,806 B2
- Document ID: US9039806B2
- Status: Granted
- Kind: B2
- Application number: 12/300,993
- Filed: 2007-05-11
- Published: 2010-01-28
- Granted: 2015-05-26
- Earliest claimed: 2006-05-15
- Assignees: International PGM Technologies
- Applicants: David B. Dreisinger; Chris A. Fleming
- Inventors: David B. Dreisinger; Chris A. Fleming
- Web page: https://patentgrep.com/patent/US9039806B2

## CPC

- C22B 11/04: {by wet processes (extraction of metal compounds by leaching in organic solutions C22B3/16; treatment or purification of solutions by liquid-liquid extraction C22B3/26)}
- C22B 3/10: Hydrochloric acid {, other halogenated acids or salts thereof}
- C22B 15/0067: {with acids or salts thereof}
- C22B 23/0415: {with acids or salt solutions except ammonium salts solutions}
- Y02P 10/20: Recycling
- C22B: PRODUCTION AND REFINING OF METALS (electrolytic C25); PRETREATMENT OF RAW MATERIALS
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

The invention provides a recycling step in an oxidative pressure leaching process for recovery of metals using halide ions, in which a portion of the leached solids are recycled back to the feed to the autoclave, to allow two or more passes through the high temperature leaching step.

## Claims

### Claim 1

A process for improving the recovery of a precious metal from a host material comprising a base metal and the precious metal, comprising the steps of:
subjecting the host material to an oxidative pressure leach process, in the presence of a leach solution bearing a halide ion constituent which is reactive with the precious metal and the base metal, at a temperature sufficient to cause at least a portion of the base metal and only a portion of the precious metal to be extracted into a leachate solution to provide leached solids;
separating the leached solids from the leachate solution to provide separated leached solids;
recovering precious metal and base metal from the leachate solution; and
recycling, after separating the leached solids from the leachate solution, at least 50% of the separated leached solids comprising at least a portion of the precious metal to the oxidative pressure leach process step, so as to increase the portion of precious metal recovered from the leachate solution,
wherein the precious metal comprises at least one of gold, platinum or palladium, and
wherein the base metal comprises at least one of nickel, copper, zinc or cobalt.

### Claim 2 (depends on 1)

The process of claim 1, wherein a recycle rate of separated leached solids recycled to the oxidative pressure leach process step is between 50% and 500%.

### Claim 3 (depends on 1)

The process of claim 1, wherein a recycle rate of separated leached solids recycled to the oxidative pressure leach process step is between 50% and 250%.

### Claim 4 (depends on 1)

The process of claim 1, wherein the oxidative pressure leach process step is carried out at 200 to 250 degrees Celsius, for 0.5 to 1.5 hours of single pass residence time, at 50 to 150 psig of oxygen overpressure, with 5 to 10 g/L chloride ion concentration.

### Claim 5 (depends on 1)

The process of claim 1, wherein the base metal comprises nickel, and wherein nickel extraction efficiency is greater than 98%.

### Claim 6 (depends on 1)

The process of claim 1, wherein the base metal comprises copper, and wherein copper extraction efficiency is greater than 98%.

### Claim 7 (depends on 1)

The process of claim 1, wherein the base metal comprises zinc, and wherein zinc extraction efficiency is greater than 98%.

### Claim 8 (depends on 1)

The process claim 1, wherein the base metal comprises cobalt, and wherein cobalt extraction efficiency is greater than 98%.

### Claim 9 (depends on 1)

The process of claim 1, wherein the precious metal comprises gold, and wherein gold extraction efficiency is greater than 90%.

### Claim 10 (depends on 1)

The process of claim 1, wherein the precious metal comprises platinum, and wherein platinum extraction efficiency is greater than 90%.

### Claim 11 (depends on 1)

The process of claim 1, wherein the precious metal comprises palladium, and wherein palladium extraction efficiency is greater than 90%.