# US 9,039,544 B2 · Golf ball and golf ball manufacturing method

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- Number: US 9,039,544 B2
- Document ID: US9039544B2
- Status: Granted
- Kind: B2
- Application number: 13/614,101
- Filed: 2012-09-13
- Published: 2014-03-13
- Granted: 2015-05-26
- Earliest claimed: 2012-09-13
- Assignees: Bridgestone Sports Co., Ltd.
- Applicants: Toshiro Wachi
- Inventors: Toshiro Wachi
- Web page: https://patentgrep.com/patent/US9039544B2

## CPC

- A63B 37/0074: {Two piece balls, i.e. cover and core}
- A63B 37/0075: {Three piece balls, i.e. cover, intermediate layer and core}
- A63B 37/0076: {Multi-piece balls, i.e. having two or more intermediate layers}
- A63B 45/00: Apparatus or methods for manufacturing balls (working of plastics or substances in a plastic state B29)
- A63B 37/0024: {Materials other than ionomers or polyurethane}
- A63B: APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT (apparatus for passive exercising, massage A61H)

## Abstract

When manufacturing golf balls having a structural component which is a molded and vulcanized material obtained by vulcanizing a rubber composition containing, as the essential ingredients, a base rubber and an unsaturated carboxylic acid or a salt thereof, the distinguishability of structural components such as cores can be enhanced by including also a soluble pigment within, and thereby coloring, the rubber composition. Moreover, vulcanized rubber powder obtained by rendering processing scrap and waste from such cores into powder can be easily decolorized by liquid washing to remove the pigment, thus enabling advantageous use of the vulcanized rubber powder as a compounding ingredient in the manufacture of other golf ball cores without affecting the color tone of the manufactured balls.

## Claims

### Claim 1

A method of manufacturing a golf ball having, as a structural component therein, a molded and vulcanized material obtained by molding and vulcanizing a rubber composition comprising a base rubber and an unsaturated carboxylic acid or a salt thereof and to which a vulcanized rubber powder has been added, the method comprising the steps of: liquid washing a soluble pigment-containing vulcanized rubber powder so as to remove the soluble pigment; and compounding the liquid-washed vulcanized rubber powder in the rubber composition.

### Claim 2 (depends on 1)

The golf ball manufacturing method of claim 1, wherein the vulcanized rubber powder has a particle size of not more than 1,000 μm.

### Claim 3 (depends on 1)

The golf ball manufacturing method of claim 1, wherein the vulcanized rubber powder has, at the time of addition to the rubber composition, a moisture content of not more than 600 ppm.

### Claim 4 (depends on 1)

The golf ball manufacturing method of claim 1, wherein the vulcanized rubber powder is processing scrap or waste from structural components of other golf balls which has been rendered into a powder.

### Claim 5 (depends on 4)

The golf ball manufacturing method of claim 4, wherein the vulcanized rubber powder is a powder formed by surface grinding golf ball cores obtained by molding and vulcanizing a rubber composition containing a base rubber, an unsaturated carboxylic acid or a salt thereof, and a soluble pigment.

### Claim 6 (depends on 1)

The golf ball manufacturing method of claim 1, wherein the soluble pigment is a water-soluble pigment and the vulcanized rubber powder containing the water-soluble pigment is liquid-washed using water.

### Claim 7 (depends on 6)

The golf ball manufacturing method of claim 6, wherein the soluble pigment is one or more water-soluble pigment selected from among naturally occurring pigments.

### Claim 8 (depends on 1)

The golf ball manufacturing method of claim 1 which produces a golf ball wherein the molded and vulcanized material obtained by molding and vulcanizing the rubber composition serves as a core.