# US 9,038,415 B2 · Composite isopipe

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- Number: US 9,038,415 B2
- Document ID: US9038415B2
- Status: Granted
- Kind: B2
- Application number: 13/699,942
- Filed: 2011-05-26
- Published: 2013-08-01
- Granted: 2015-05-26
- Earliest claimed: 2010-05-28
- Assignees: Corning Incorporated
- Applicants: Nikolay Anatolyevich Panin
- Inventors: Nikolay Anatolyevich Panin
- Web page: https://patentgrep.com/patent/US9038415B2

## CPC

- C03B 17/064: {by the overflow downdraw fusion process; Isopipes therefor}
- C03B: MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES

## Abstract

A fusion down-draw method for making a glass sheet using a forming body comprising an upper part (101) made of a first material and a lower part (103) made of a second material, where the first material has lower creep rate than the second material at the normal operating temperature of the forming body, and an fusion down-draw forming apparatus comprising such forming body. The invention is advantageous in that it solves the issues of internal stress and long-term creep issue of a unitary forming body made of a single material such as zircon.

## Claims

### Claim 1

An apparatus for making a glass sheet using a fusion down-draw process, comprising a forming body having an upper part (101) made of a first material and a lower part (103) made of a second material below said upper part (101), wherein the upper part (101) comprises two upper trough walls (112, 114) and a trough bottom defining a trough space (105) for accepting molten glass, and the lower part (103) has a wedge-shaped cross-section having two major surfaces sloping downwardly to join at a root, and the side walls of the upper part (101) and the lower part (103) form substantially two continuous forming surfaces on which streams of molten glass can flow downwardly to join at the root (108) during normal operation, the first material has a creep rate at 1200° C. of CR1, and the second material has a creep rate at 1200° C. of CR2, and CR1<CR2,
wherein the first material consists essentially of α-SiC, silicon nitride or silicon oxynitride, and the second material consists essentially of zircon.

### Claim 2 (depends on 1)

An apparatus for making a glass sheet according to claim 1, wherein CR2/CR1>103.

### Claim 3 (depends on 1)

An apparatus for making a glass sheet according to claim 1, further comprising a furnace enclosing the forming body adapted for maintaining the upper part (101) of the forming body at a substantially constant temperature, and maintaining the lower part (103) of the forming body to have a temperature gradient of deltaT=Ttop−Troot, where Ttop is the temperature of the top of the lower part (103), Troot is the temperature of the root (108) of the lower part (103), and deltaT≧10° C.

### Claim 4 (depends on 1)

An apparatus for making a glass sheet according to claim 1, wherein CR2≦1×10−5 hour−1 at 1200° C. and a load of 200 psi.

### Claim 5 (depends on 1)

An apparatus for making a glass sheet according to claim 1, wherein CR1≧1×10−13 hour−1 at 1200° C. and a load of 200 psi.

### Claim 6 (depends on 1)

An apparatus for making a glass sheet according to claim 1, wherein the lower part (103) has a wing (104, 106) at each end supported by a pier block (105, 107).

### Claim 7 (depends on 1)

An apparatus for making a glass sheet according to claim 1, wherein each of the pier blocks (105, 107) exerts a compressive force F, F′ to the end of the lower part (103), such that a compressive moment exists inside the lower part (103) to reduce sagging of the lower part (103) of the forming body.

### Claim 8 (depends on 1)

An apparatus for making a glass sheet according to claim 1, wherein the upper part (101) further comprises a cavity.

### Claim 9 (depends on 8)

An apparatus for making a glass sheet according to claim 8, further comprising a heating element inside the cavity (115) adapted for heating the forming body.

### Claim 10 (depends on 1)

An apparatus for making a glass sheet according to claim 1, wherein the bottom surface of the upper part (101) and the top surface of the lower part (103) have reciprocal, interlocking features formed thereon.

### Claim 11

A method for making a glass sheet comprising the following steps:
(A) providing a glass melt;
(B) providing a forming body having an upper part (101) made of a first material and a lower part (103) made of a second material below said upper part (101), wherein the upper part (101) comprises two upper trough sidewalls and a trough bottom surface defining a trough space (105) for accepting molten glass, and the lower part (103) has a wedge-shaped cross-section having two major surfaces sloping downwardly to join at a root, and the external side surfaces of the upper part (101) and the lower part (103) form substantially two continuous forming surfaces on which streams of molten glass can flow downwardly to join at the root (108) during normal operation, the first material has a creep rate at 1200° C. of CR1, and the second material has a creep rate at 1200° C. of CR2, and CR1<CR2;
(C) supplying the glass melt into the trough of the forming body, and allowing the glass melt to overflow the top surfaces of the trough sidewalls, flow over the two forming surfaces, and join at the root (108) to form a unitary glass ribbon;
(D) drawing the glass ribbon below the root (108) to form the glass sheet,
wherein the first material consists essentially of α-SiC, silicon nitride, or silicon oxynitride, and the second material consists essentially of zircon.

### Claim 12 (depends on 11)

A method for making a glass sheet according to claim 11, wherein CR2/CR1>103.

### Claim 13 (depends on 11)

A method according to claim 11, further comprising the following steps (E) and (F):
(E) maintaining the upper part (101) of the forming body at a substantially constant temperature by a muffle; and
(F) maintaining the lower part (103) of the forming body to have a temperature gradient of deltaT=Ttop−Troot, where Ttop is the temperature of the top of the lower part (103), Troot is the temperature of the root (108) of the lower part (103), and deltaT≧10° C.

### Claim 14 (depends on 11)

A method according to claim 11, wherein CR2≦1×10−5 hour−1 at 1200° C. and a load of 200 psi.

### Claim 15 (depends on 11)

A method according to claim 11, wherein CR1≧1×10−13 hour−1 at 1200° C. and a load of 200 psi.

### Claim 16 (depends on 11)

A method according to claim 11, wherein the lower part (103) has a wing (104, 106) at each end supported by a pier block (105, 107).

### Claim 17 (depends on 11)

A method for making a glass sheet according to claim 11, further comprising a compressive force F, F′ to each end of the lower part (103) through the pier blocks (105, 107) such that a compressive moment exists inside the lower part (103) to reduce sagging of the lower part (103) of the forming body.

### Claim 18 (depends on 11)

A method for making a glass sheet according to the preceding claim 11, wherein the upper part (101) further comprises a cavity.

### Claim 19 (depends on 11)

A method for making a glass sheet according to claim 11, further comprising heating the upper part (101) of by a heating element inside the cavity.

### Claim 20 (depends on 11)

A method for making a glass sheet according to claim 11, wherein the bottom surface of the upper part (101) and the top surface of the lower part (103) have reciprocal, interlocking features fonned thereon.

### Claim 21 (depends on 11)

A method for making a glass sheet according to claim 11, wherein step (B) comprises:
(B1) obtaining an upper part (101) made of the first material of a used forming body;
(B2) obtaining a new lower part (103) made of the second material; and
(B3) stacking the upper part (101) over the lower part (103) to provide the forming body.

### Claim 22

An apparatus for making a glass sheet using a fusion clown-draw process, comprising a forming body having an upper part (101) made of a first material and a lower part (103) made of a second material below said upper part (101), wherein the upper part (101) comprises two upper trough walls (112, 114) and a trough bottom defining a trough space (105) for accepting molten glass, and the lower part (103) has a wedge-shaped cross-section having two major surfaces sloping downwardly to join at a root, and the side walls of the upper part (101) and the lower part (103) form substantially two continuous forming surfaces on which streams of molten glass can flow downwardly to join at the root (108) during normal operation, the first material has a creep rate at 1200° C. of CR1, and the second material has a creep rate at 1200° C. of CR2, and CR1 CR2,
wherein the bottom surface of the upper part (101) and the top surface of the lower part (103) have reciprocal, interlocking features formed thereon.

### Claim 23

A method for making a glass sheet comprising the following steps:
(A) providing a glass melt;
(B) providing a forming body having an upper part (101) made of a first material and a lower part (103) made of a second material below said upper part (101), wherein the upper part (101) comprises two upper trough sidewalls and a trough bottom surface defining a trough space (105) for accepting molten glass, and the lower part (103) has a wedge-shaped cross-section having two major surfaces sloping downwardly to join at a root, and the external side surfaces of the upper part (101) and the lower part (103) form substantially two continuous forming surfaces on which streams of molten glass can flow downwardly to join at the root (108) during normal operation, the first material has a creep rate at 1200° C. of CR1, and the second material has a creep rate at 1200° C. of CR2, and CR1<CR2;
(C) supplying the glass melt into the trough of the forming body, and allowing the glass melt to overflow the top surfaces of the trough sidewalls, flow over the two forming surfaces, and join at the root (108) to form a unitary glass ribbon; and
(D) drawing the glass ribbon below the root (108) to form the glass sheet,
wherein the bottom surface of the upper part (101) and the top surface of the lower part (103) have reciprocal, interlocking features formed thereon.
