Back to results
US 9,006,457 B2Granted
Reactive ionic liquids
AssigneeBASF SE
InventorsMichael Schmidt, Nikolai (Mykola) Ignatyev, William-Robert Pitner
Life of this patent
Estimating the term…
Abstract
The invention relates to reactive ionic liquids containing organic cations with groups or substituents which are susceptible to electrochemical reduction and anions obtained from fluoroalkyl phosphates, fluoroalkyl phosphinates, fluoroalkyl phosphonates, acetates, triflates, imides, methides, borates, phosphates and/or aluminates, for use in electrochemical cells, such as lithium ion batteries and double-layer capacitors.
Claims17
Ionic liquids of the general formula I
- K+A− (I)
- in which:
- K+ denotes at least one cation selected from the group consisting of the general formula IV
- where
- X denotes CH2;
- R5 denotes —(CH2)n—O—C(O)—R— where n=2;
- and
- R denotes CH3;
- and
- A− denotes at least one anion selected from the group consisting of
- [FyP(CmF2m+1)6−y]−;
- (CmF2m+1)2P(O)O−;
- (CmF2m+1)P(O)O22−;
- O—C(O)—CmF2m+1;
- O—S(O)2—CmF2m+1;
- N(C(O)—CmF2m+1)2;
- N(S(O)2—CmF2m+1)2;
- N(C(O)—CmF2m+1)(S(O)2—CmF2m+1);
- N(C(O)—CmF2m+1)(C(O)F);
- N(S(O)2—CmF2m+1)(S(O)2F);
- N(S(O)2F)2;
- C(C(O)—CmF2m+1)3;
- C(S(O)2—CmF2m+1)3;
- where y=1, 2, 3, 4 or 5 and m=1 to 8, where some of the CF2 groups may be replaced by O, S(O)2, NR or CH2, and where
- denotes a 1,2- or 1,3-diol, a 1,2- or 1,3-dicarboxylic acid or a 1,2- or 1,3-hydroxycarboxylic acid;
- Y denotes B or Al;
- R1 to R4 denote halogen, and/or a fluorinated or non-fluorinated alkoxy or carboxyl radical.
24 more elements
Dependencies are inferred from the claim text.