# US 9,006,139 B2 · Active compound combinations > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,006,139 B2 - Document ID: US9006139B2 - Status: Granted - Kind: B2 - Application number: 14/462,945 - Filed: 2014-08-19 - Published: 2014-12-04 - Granted: 2015-04-14 - Earliest claimed: 2009-09-14 - Assignees: Bayer Intellectual Property GmbH - Applicants: Thomas Seitz; Ulrike Wachendorff-Neumann; Peter Dahmen - Inventors: Thomas Seitz; Ulrike Wachendorff-Neumann; Peter Dahmen - Web page: https://patentgrep.com/patent/US9006139B2 ## CPC - A01N 43/90: having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system - A01N 25/02: containing liquids as carriers, diluents or solvents - A01N 39/00: Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group [IMAGE cpc-sch-A01N-0940.gif] or [IMAGE cpc-sch-A01N-0941.gif], e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone - A01N 43/16: with oxygen as the ring hetero atom - A01N 43/40: six-membered rings - A01N 43/54: 1,3-Diazines; Hydrogenated 1,3-diazines - A01N 43/56: 1,2-Diazoles; Hydrogenated 1,2-diazoles - A01N 43/78: 1,3-Thiazoles; Hydrogenated 1,3-thiazoles - A01N 43/84: six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4 - A01N 47/12: containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring - A01N 57/12: containing acyclic or cycloaliphatic radicals - A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS ## Abstract The present invention relates to compositions, in particular within a fungicide composition, which comprises (A) a dithiino-tetracarboximide of formula (I) and a further fungicidally active compound (B). Moreover, the invention relates to a method for curatively or preventively controlling the phytopathogenic fungi of plants or crops, to the use of a combination according to the invention for the treatment of seed, to a method for protecting a seed and to the treated seed. ## Claims ### Claim 1 A composition comprising (A) at least one dithiino-tetracarboximide of formula (I) in which R1 and R2 are identical and represent methyl, ethyl, n-propyl or isopropyl, and n represents 0 or 1, or an agrochemically acceptable salt thereof, and (B) at least one further active compound selected from the group consisting of benthiavalicarb, dimethomorph, iprovalicarb, mandipropamid, and valifenalate. ### Claim 2 (depends on 1) The composition according to claim 1, wherein the compound of formula (1) is 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c′]dipyrrole-1,3,5,7(2H,6H)-tetrone. ### Claim 3 (depends on 1) The composition according to claim 1 further comprising auxiliaries, solvents, carriers, surfactants or extenders. ### Claim 4 (depends on 1) The composition according to claim 1 wherein the at least one dithiino-tetracarboximide and the least one further active compound are present in a synergistically effective weight ratio. ### Claim 5 (depends on 4) The composition according to claim 4 wherein the at least one dithiino-tetracarboximide and the least one further active compound are present in a weight ratio of 100:1 to 1:100. ### Claim 6 (depends on 4) The composition according to claim 4 wherein the at least one dithiino-tetracarboximide and the at least one further active compound are present in a weight ratio of 50:1 to 1:50. ### Claim 7 (depends on 4) The composition according to claim 4 wherein the at least one dithiino-tetracarboximide and the at least one further active compound are present in a weight ratio of 20:1 to 1:20. ### Claim 8 (depends on 2) The composition of claim 2, wherein the (B) at least one further active compound is benthiavalicarb. ### Claim 9 (depends on 8) The composition according to claim 8 wherein the 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c′]dipyrrole-1,3,5,7(2H,6H)-tetrone and the benthiavalicarb are present in a synergistically effective weight ratio. ### Claim 10 (depends on 9) The composition according to claim 9 wherein the 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c′]dipyrrole-1,3,5,7(2H,6H)-tetrone and the benthiavalicarb are present in a weight ratio of 100:1 to 1:100. ### Claim 11 (depends on 9) The composition according to claim 9 wherein the 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c′]dipyrrole-1,3,5,7(2H,6H)-tetrone and the benthiavalicarb are present in a weight ratio of 50:1 to 1:50. ### Claim 12 (depends on 9) The composition according to claim 9 wherein 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c∝]dipyrrole-1,3,5,7(2H,6H)-tetrone and the benthiavalicarb are present in a weight ratio of 30:1 to 1:30. ### Claim 13 (depends on 9) The composition according to claim 9 wherein 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c′]dipyrrole-1,3,5,7(2H,6H)-tetrone and the benthiavalicarb are present in a weight ratio of 20:1 to 1:20. ### Claim 14 (depends on 1) A method for controlling phytopathogenic fungi in crop protection comprising applying the composition according to claim 1 to seed, to a plant, to a fruit of the plant, or to soil on which the plant grows or soil from which the seed, the plant, or the fruit of the plant grows. ### Claim 15 (depends on 14) The method according to claim 14, wherein the composition is applied to the soil on which the seed, the plant, or the fruit of the plant grows or from which the seed, the plant, or the fruit of the plant grows. ### Claim 16 (depends on 14) The method according to claim 14, wherein the composition is applied as a foliar treatment. ### Claim 17 (depends on 16) The method according to claim 16 wherein the composition is applied at a rate from 0.1 to 10 000 g/ha. ### Claim 18 (depends on 14) The method according to claim 14 wherein the composition is applied to the seed. ### Claim 19 (depends on 18) The method according to claim 18 wherein the composition is applied at rate of from 2 g to 200 g per 100 kg of seed. ### Claim 20 (depends on 14) The method according to claim 14 wherein the plant is a transgenic plant. ### Claim 21 (depends on 14) The method according to claim 14 wherein the seed is seed of a transgenic plant. ### Claim 22 (depends on 14) The method according to claim 14 wherein the phytopathogenic fungi is selected from the group consisting of Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes. ### Claim 23 (depends on 14) The method according to claim 14 wherein the composition is applied to the seed, plant, fruit or soil prior to attack by phytopathogenic fungi. ### Claim 24 (depends on 14) The method according to claim 14 wherein the plant is selected from the group consisting of cereals, maize, cotton, soya bean, rice, potatoes, sunflowers, beans, coffee, beets, peanuts, oilseed rape, poppies, olives, coconuts, cacao, sugar cane, tobacco, vegetables, lawn and ornamental plants. ### Claim 25 (depends on 14) The method according to claim 14 wherein the plant is selected from the group consisting of cereals, maize and rice.