# US 9,004,648 B2 · Inkjet printheads containing epoxy adhesives and methods for fabrication thereof > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,004,648 B2 - Document ID: US9004648B2 - Status: Granted - Kind: B2 - Application number: 13/957,084 - Filed: 2013-08-01 - Published: 2015-02-05 - Granted: 2015-04-14 - Earliest claimed: 2013-08-01 - Assignees: Xerox Corporation - Applicants: Xerox Corporation - Inventors: Yanjia Zuo; John R. Andrews; Pratima Gattu Naga Rao; Mandakini Kanungo; Hong Zhao; Santokh S. Badesha - Web page: https://patentgrep.com/patent/US9004648B2 ## CPC - B41J 2/14: Structure thereof {only for on-demand ink jet heads} - B32B 37/00: Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding - B41J 2/161: {of film type, deformed by bending and disposed on a diaphragm} - B41J 2/1623: {bonding and adhesion} - B41J 2/1634: {laser machining} - B32B 2250/03: 3 layers - B32B 2333/08: Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate - B32B 2363/00: Epoxy resins - B41J 2002/14403: {including a filter} - B41J: TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS - B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM ## Abstract Inkjet printheads containing a first plate, a second plate, and a cured adhesive composition disposed between and bonding the first plate and the second plate. The cured adhesive composition has a glass transition temperature of greater than about 115° C. and is stable when exposed to acrylate monomer. Also, inkjet printheads having a first plate, a second plate, and a cured thin film adhesive disposed between and bonding to both of the first plate and the second plate. The cured thin film adhesive contains a polyimide film disposed between a cured first adhesive layer and a cured second adhesive layer. Methods of preparing such inkjet printheads. ## Claims ### Claim 1 An inkjet printhead comprising: a first plate; a second plate; a cured adhesive composition disposed between and bonding at least one of the first plate and the second plate, wherein the cured adhesive composition has a Tg of greater than about 115° C. and is stable when exposed to acrylate monomer, and wherein the cured adhesive composition is prepared by curing an epoxy resin mixture comprising an epoxy novolac and an amine at a temperature of less than about 200° C. ### Claim 2 (depends on 1) The inkjet printhead of claim 1, wherein the epoxy novolac is an epoxy bisphenol A novolac and the amine is isophorone diamine. ### Claim 3 (depends on 1) The inkjet printhead of claim 1, wherein the epoxy novolac has an epoxide functionality greater than 2 to about 8. ### Claim 4 (depends on 1) The inkjet printhead of claim 1, wherein the amine comprises at least two amino groups. ### Claim 5 (depends on 1) The inkjet printhead of claim 1, wherein the first plate comprises aluminum, polyimide, stainless steel, or gold plated stainless steel and the second plate comprises aluminum, polyimide, stainless steel, or gold plated stainless steel. ### Claim 6 (depends on 1) The inkjet printhead of claim 1, further comprising a UV ink or a UV ink gel. ### Claim 7 (depends on 1) The inkjet printhead of claim 1, wherein there is substantially no squeeze-out of the epoxy resin mixture as it is cured. ### Claim 8 (depends on 1) The inkjet printhead of claim 1, wherein the epoxy resin mixture has a storage modulus of about 100 MPa to about 1500 MPa at about 20° C. and of about 3 MPa to about 700 MPa at about 120° C. ### Claim 9 An inkjet printhead comprising: a first plate; a second plate; a cured thin film adhesive disposed between and bonding to both of the first plate and the second plate, wherein the cured thin film adhesive comprises a metal layer or a polymer film disposed between a cured first adhesive layer and a cured second adhesive layer, wherein curing of a first adhesive layer and a second adhesive layer at a temperature of less than about 200° C. while the first adhesive layer, metal layer or polymer film, and second adhesive layer are disposed between the first plate and the second plate results in the bonding of the cured thin film adhesive to the first plate and the second plate and both of the cured first adhesive layer and the cured second adhesive layer have a Tg of greater than about 115° C. and are stable when exposed to acrylate monomer, and wherein at least one of the first adhesive layer and the second adhesive layer comprises an epoxy novolac and an amine. ### Claim 10 (depends on 1) The inkjet printhead of claim 1, wherein the lapshear strength of the cured thin film adhesive between two stainless steel surfaces, a stainless steel surface to a polyimide surface, or a polyimide surface to a polyimide surface is greater than about 200 psi at temperatures between about 25° C. and about 140° C., wherein the first adhesive layer has a thickness of between about 3 microns and about 9 microns. ### Claim 11 (depends on 9) The inkjet printhead of claim 9, wherein the epoxy novolac is an epoxy bisphenol A novolac and the amine is isophorone diamine. ### Claim 12 (depends on 9) The inkjet printhead of claim 9, wherein the epoxy novolac has an epoxide functionality greater than 2 to about 8. ### Claim 13 (depends on 9) The inkjet printhead of claim 9, wherein the amine comprises at least two amino groups. ### Claim 14 (depends on 9) The inkjet printhead of claim 9, wherein the first plate comprises aluminum, polyimide, stainless steel, or gold plated stainless steel and the second plate comprises aluminum, polyimide, stainless steel, or gold plated stainless steel. ### Claim 15 (depends on 9) The inkjet printhead of claim 9, further comprising a UV ink or a UV ink gel. ### Claim 16 (depends on 9) The inkjet printhead of claim 9, wherein there is substantially no squeeze-out of the first adhesive layer and the second adhesive layer as they are cured. ### Claim 17 A method of producing an inkjet printhead comprising: placing a thin film adhesive between a first plate and a second plate; curing at a temperature of less than about 200° C. the thin film adhesive as it is in contact with both surface of the first plate and the second plate, thereby bonding the cured thin film adhesive to both of the first plate and the second plate, wherein the cured thin film adhesive comprises a metal layer or a polymer film disposed between a cured first adhesive layer and a cured second adhesive layer, wherein the cured first adhesive layer and the cured second adhesive layer have a Tg of greater than about 115° C. and are stable when exposed to acrylate monomer, and wherein at least one of the first adhesive layer and the second adhesive layer comprises an epoxy novolac and an amine. ### Claim 18 (depends on 17) The method of claim 17, further comprising preparing the thin film adhesive by applying an epoxy resin mixture to at least one surface of a polyimide film and drying the epoxy resin mixture without curing the epoxy resin mixture. ### Claim 19 (depends on 17) The method of claim 17, further comprising laser cutting the thin film adhesive to conform to a region where the first plate overlays the second plate. ### Claim 20 (depends on 17) The method of claim 17, wherein the curing is carried out at between about 180° C. and about 190° C. for between about 60 minutes and about 90 minutes.