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US 9,000,244 B2Granted
Process for production of biodiesel
AssigneeArisdyne Systems, Inc.
InventorsOleg Kozyuk, Peter Reimers, Paul A. Reinking
Life of this patent
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Abstract
A multi-stage reactor system for preparing biodiesel is used to increase efficiency and yield and reduce impurities. A three-stage transesterification reaction for preparing biodiesel can include one high-shear cavitation reactor and two low-shear cavitation reactors, preferably in series, and optionally one or more separation vessels for removing waste and recycling triglyceride feedstock, catalyst and alcohol to the high-shear cavitation reactor.
Claims16
A process for preparing biodiesel comprising:
- (a) reacting a triglyceride feedstock, alcohol and catalyst in a high-shear reactor to form a first intermediate reacted mixture, wherein the high-shear reactor is a cavitation reactor operating at a shear rate of greater than 8,000 s−1;
- (b) reacting the first intermediate reacted mixture in a low-shear reactor to form a second intermediate reacted mixture;
- (c) removing glycerol and unreacted alcohol from the second intermediate reacted mixture to form a purified second intermediate reacted mixture, the glycerol and unreacted alcohol removed from the second intermediate reacted mixture being recycled back to the high-shear reactor;
- (d) reacting the second intermediate reacted mixture in a second low-shear reactor to form a crude biodiesel reacted mixture, wherein the low-shear and the second low-shear reactor are operating at a shear rate of less than 1,000 s−1.
1 more element
A three-stage transesterification reaction for preparing biodiesel comprising:
- (a) reacting a triglyceride feedstock, alcohol and catalyst in a high-shear reactor to form a first intermediate reacted mixture, wherein the high-shear reactor is a cavitation reactor operating at a shear rate of greater than 8,000 s−1, and wherein the ratio of the catalyst to the triglyceride feedstock is less than 1.9 by weight;
- (b) reacting the first intermediate reacted mixture in a low-shear reactor to form a second intermediate reacted mixture;
- (c) passing the second intermediate reacted mixture through a separation vessel to form a purified second intermediate reacted mixture;
- removing glycerol and unreacted alcohol from the second intermediate reacted mixture to form a purified second intermediate reacted mixture, the glycerol and unreacted alcohol removed from the second intermediate reacted mixture being recycled back to the high-shear reactor;
- (d) adding additional non-recycled alcohol and additional non-recycled catalyst to the purified second intermediate reacted mixture, wherein the ratio of the total catalyst to the triglyceride feedstock is less than 0.8 by weight;
- (e)) reacting the purified second intermediate reacted mixture in a second low-shear reactor to form a crude biodiesel reacted mixture;
- wherein the low-shear and the second low-shear reactor are operating at a shear rate of less than 1,000 s−1,
- (f) passing the crude biodiesel reacted mixture through a separation vessel to form a purified biodiesel product that product meets the triglyceride feedstock conversion level required by ASTM 6751.
5 more elements
Dependencies are inferred from the claim text.