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US 9,000,228 B2Granted
Method for producing vinyl ether
AssigneeNippon Carbide Industries Co., Inc.
InventorsShinichi Kakinuma, Shinya Mita, Masahiro Murotani
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Abstract
A method for efficiently producing high purity vinyl ether represented by the following formula (1) from tertiary alcohol having a low reactivity comprising by reacting acetylene and a tertiary alcohol in the presence of a base using, as a solvent, a cyclic urea compound or glyme compound or mixture thereof: is provided.
Claims9
A method for producing vinyl ether represented by the formula (1):
- from acetylene and a tertiary alcohol in the presence of a base, characterized in that;
- the tertiary alcohol is an alcohol represented by the formula (2):
- and that a reaction is carried out by using, as a solvent, a cyclic urea compound represented by the formula (3):
- wherein Z indicates
- wherein, in the above formulae (1) to (3),
- R1 to R3 independently indicate C1 or more hydrocarbon groups represented by the following formula (5)
- wherein
- X is a carbon atom,
- V and W independently indicate hydrogen or a substituted or unsubstituted C1 or more hydrocarbon group, provided that the case where the carbon directly bonded with X of V or W has a primary or secondary hydroxyl group in a cis arrangement with a hydroxyl group of the tertiary alcohol (2), as a substituent group is excluded, and
- Y indicates hydrogen or a substituted or unsubstituted C1 or more hydrocarbon group, provided that the case where the carbon of Y directly bonded with X has a primary or secondary hydroxyl group in a cis arrangement with a hydroxyl group of the tertiary alcohol (2) as a substituent group is excluded;
- or one group selected form a tertiary hydroxyl group, alkoxy group and alkyl sulfanyl group,
- two or more of R1 to R3 may be condensed to form a ring, provided that the case where two or more of R1 to R3 are condensed to form an aromatic ring is excluded,
- further, R4 to R9 independently indicate hydrogen or a C1 or more alkyl group or —(CH2CH2O)mR10,
- R10 indicates hydrogen or a C1 to C4 saturated or unsaturated hydrocarbon group,
- m is an integer of 1 or more, and n is an integer of 1 to 4.
12 more elements
Dependencies are inferred from the claim text.