A process for preparing a rubber composition that is free of zinc or that contains less than 0.5 phr of zinc, and wherein zinc has not been replaced with another metal, comprising, incorporating at least, by kneading, into at least (i) one diene elastomer, (ii) an inorganic filler as reinforcing filler, (iii) a blocked mercaptosilane of general formula I below:
- (R3O)R2R1—Si—Z—S—C(═O)-A
- in which:
- R1 and R2, which are identical or different, represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms;
- R3 represents a monovalent hydrocarbon-based group chosen from linear or branched alkyls having from 1 to 4 carbon atoms;
- A represents hydrogen or a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms;
- Z represents a divalent bonding group comprising from 1 to 18 carbon atoms, and (iv) a sulphur-based vulcanization system.