# US 8,999,875 B2 · Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use

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- Number: US 8,999,875 B2
- Document ID: US8999875B2
- Status: Granted
- Kind: B2
- Application number: 13/700,098
- Filed: 2011-05-26
- Published: 2013-03-21
- Granted: 2015-04-07
- Earliest claimed: 2010-05-28
- Assignees: Basell Polyolefine GmbH
- Applicants: Fabiana Fantinel; Shahram Mihan; Rainer Karer; Volker Fraaije
- Inventors: Fabiana Fantinel; Shahram Mihan; Rainer Karer; Volker Fraaije
- Web page: https://patentgrep.com/patent/US8999875B2

## CPC

- C08F 210/16: Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08L 23/0815: {with aliphatic 1-olefins containing one carbon-to-carbon double bond}
- C08F 4/61912: {in combination with an organoaluminium compound}
- C08F 4/61916: {supported on a carrier, e.g. silica, MgCl2, polymer}
- C08F 4/61925: {two cyclopentadienyl rings being mutually non-bridged}
- Y10S 526/943: Polymerization with metallocene catalysts
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

The invention refers to a process for preparing a supported catalyst system for the polymerization of olefins comprising at least one active catalyst component on a support, the process comprising A) impregnating a dry porous support component with a mixture comprising at least one precatalyst, at least one cocatalyst, and a first solvent, such that the total volume of the mixture is from 0.8 to 2.0 times the total pore volume of the support component, and B) thereafter, adding a second solvent in an amount of more than 1.5 times the total pore volume of the support component. The invention refers further to a catalyst system made by this process and the use of this catalyst system for polymerization or copolymerization of olefins.

## Claims

### Claim 1

A process comprising:
preparing a catalyst system, wherein the preparing step comprises the steps of:
A) impregnating a porous support component with a mixture comprising:
(a) a precatalyst, wherein the precatalyst comprises a metallocene and an iron complex,
(b) at least one cocatalyst, and
(c) a first solvent to form an immobilized catalyst component, wherein the porous support component has a total pore volume from 0.1 to 10 cm3/g, and a residual moisture content less than 5 wt. %, based upon the total weight of the porous support component, wherein the total volume of the mixture is from 0.8 to 2.0 times the total pore volume of the porous support component;
B) adding a second solvent to the immobilized catalyst component, wherein the second solvent is a C5-16 alkane; and
C) removing the solvent by filtration or evaporation.

### Claim 2 (depends on 1)

The process of claim 1, wherein the first solvent is selected from the group consisting of a C6-16 aromatic hydrocarbon, a C1-10-alkyl substituted C6-16 aromatic hydrocarbon, a C5-20 cycloalkane, and a C1-10-alkyl substituted C5-10 cycloalkane.

### Claim 3 (depends on 2)

The process of claim 2, wherein the first solvent is toluene, and the second solvent is heptane.

### Claim 4 (depends on 1)

The process of claim 1, wherein the first solvent is added such that the total volume of the mixture is 1.0 to 2.0 times the total pore volume of the porous support component.

### Claim 5 (depends on 1)

The process of claim 1, wherein the support component is a silica gel.

### Claim 6 (depends on 1)

The process of claim 1, wherein the cocatalyst is an aluminoxane.

### Claim 7 (depends on 1)

The process of claim 1, wherein the metallocene is present in the catalyst system in an amount from 1 to 200 μmol per gram of porous support component.

### Claim 8 (depends on 7)

The process of claim 7, wherein the iron complex is present in the catalyst system in an amount from 0.1 to 20 μmol per gram of porous support component.

### Claim 9 (depends on 1)

The process of claim 1, comprising the step of polymerizing or copolymerizing at least one alpha-olefin in the presence of the catalyst system.