Bis-quaternary ammonium salt corrosion inhibitors
AssigneeNalco Company
InventorsKevin M. Henry, Keith D. Hicks
Life of this patent
Estimating the term…
Abstract
Bis-quaternary ammonium salts of formula wherein Y is a group of formula NR11R12+X− or NR7; n is 0 or 1; p is 1 or 2; r and q are independently 2, 3 or 4; X is an anionic counterion and R1R2R3N— and R4R5R6N— are independently selected from groups of formula —N(R13)2R8, —N(R14)3, —N(R13)3, —N(R13)2(CH2)qOC(O)R9, and wherein R7, R11 and R12 are independently selected from C1-C18 alkyl; R8, R9, R10 and R15 are independently selected from C8-C18 alkyl and C8-C18 alkenyl; R13 is C1-C4 alkyl; R14 is C2-C4 hydroxyalkyl; and R11 is selected from C2-C4 hydroxyalkyl, C2-C4 aminoalkyl and groups of formula —CH2)rNHC(O)R15 are effective inhibitors of corrosion and biofouling of metallic surfaces in contact with gas- and oil-field fluids.
Claims12
A method of inhibiting corrosion and biofouling of metallic surfaces in contact with a fluid encountered in petroleum operations comprising adding to the fluid up to about 1,000 ppm of one or more bis-quaternary ammonium salts of formula
- wherein Y is a group of formula NR11R12+X− or NR7;
- n is 1;
- p is 1 or 2;
- r and q are independently 2, 3 or 4;
- X is an anionic counterion, Z is an anionic counterion, and R1R2R3N— and R4R5R6N— are independently selected from groups of formula—N(R13)2R8, —N(R14)3, —N(R13)3, —N(R13)2(CH2)qOC(O)R9,
- wherein R7, R11 and R12 are independently selected from C1-C18 alkyl;
- R8, R9, R10 and R15 are independently selected from C8-C18 alkyl and C8-C18 alkenyl;
- R13 is C1-C4 alkyl;
- R14 is C2-C4 hydroxyalkyl;
- and wherein said petroleum operation is primary, secondary, and/or tertiary oil recovery.
Dependencies are inferred from the claim text.