Fluororesin and riser pipe
AssigneeDaikin Industries, Ltd.
InventorsTakahiro Kitahara, Takuma Kawabe
Life of this patent
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Abstract
An object of the present invention it to provide a novel fluororesin that has excellent mechanical strength and chemical resistance, and very low permeability at high temperature. The fluorine resin a copolymer that includes copolymerized units derived from tetrafluoroethylene, vinylidene fluoride, and an ethylenically unsaturated monomer other than tetrafluoroethylene and vinylidene fluoride. The fluororesin has a storage modulus E′, as measured at 170° C. by a dynamic viscoelasticity analysis, in the range of 60 to 400 MPa.
Claims9
A fluororesin comprising
- a copolymer that consists of copolymerized units derived from tetrafluoroethylene, vinylidene fluoride, and an ethylenically unsaturated monomer other than tetrafluoroethylene and vinylidene fluoride,
- wherein the fluororesin has a storage modulus E′, as measured at 170° C. by a dynamic viscoelasticity analysis, in the range of 60 to 400 MPa and
- wherein the copolymer consists of 55.0 to 90.0 mol % of copolymerized units derived from tetrafluoroethylene, 5.0 to 44.9 mol % of copolymerized units derived from vinylidene fluoride, and 0.1 to 10.0 mol % of copolymerized units derived from an ethylenically unsaturated monomer other than tetrafluoroethylene and vinylidene fluoride, the ethylenically unsaturated monomer being represented by the formula (1):
- CX1X2═CX3(CF2)nX4
- wherein X1, X2, X3, and X4, which may be the same or different, each represent H, F, or Cl, and n is an integer of 0 to 8.
A fluororesin comprising
- a copolymer that consists of copolymerized units derived from tetrafluoroethylene, vinylidene fluoride, and an ethylenically unsaturated monomer other than tetrafluoroethylene and vinylidene fluoride,
- wherein the fluororesin has a storage modulus E′, as measured at 170° C. by a dynamic viscoelasticity analysis, in the range of 60 to 400 MPa, and
- wherein the copolymer consists of 55.0 to 90.0 mol % of copolymerized units derived from tetrafluoroethylene, 9.2 to 44.2 mol % of copolymerized units derived from vinylidene fluoride, and 0.1 to 0.8 mol % of copolymerized units derived from an ethylenically unsaturated monomer represented by the formula (2):
- CF2═CF—ORf1
- wherein Rf1 represents a C1-3 alkyl group or a C1-3 fluoro alkyl group.
A fluororesin comprising
- a copolymer that comprises copolymerized units derived from tetrafluoroethylene, vinylidene fluoride, and an ethylenically unsaturated monomer other than tetrafluoroethylene and vinylidene fluoride,
- wherein the fluororesin has a storage modulus E′, as measured at 170° C. by a dynamic viscoelasticity analysis, in the range of 60 to 400 MPa,
- wherein the copolymer comprises 55.0 to 90.0 mol % of copolymerized units derived from tetrafluoroethylene, 5.0 to 44.8 mol % of copolymerized units derived from vinylidene fluoride, 0.1 to 10.0 mol % of copolymerized units derived from a first ethylenically unsaturated monomer other than tetrafluoroethylene and vinylidene fluoride, and 0.1 to 0.8 mol % of copolymerized units derived from a second ethylenically unsaturated monomer, the first ethylenically unsaturated monomer being represented by the formula (1):
- CX1X2═CX3(CF2)nX4
- wherein X1, X2, X3, and X4, which may be the same or different, each represent H, F, or Cl, and n is an integer of 0 to 8, the second ethylenically unsaturated monomer being represented by the formula (2):
- CF2═CF—ORf1
- wherein Rf1 represents a C1-3 alkyl group or a C1-3 fluoro alkyl group.
Dependencies are inferred from the claim text.