Silicide compositions containing alkali metals and methods of making the same
AssigneesSigna Chemistry, Inc., Board of Trustees of Michigan State University
InventorsMichael Lefenfeld, James L. Dye
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AssigneesSigna Chemistry, Inc., Board of Trustees of Michigan State University
InventorsMichael Lefenfeld, James L. Dye
Estimating the term…
The invention relates to a method of making alkali metal silicide compositions, and the compositions resulting from the method, comprising mixing an alkali metal with silicon and heating the resulting mixture to a temperature below about 475° C. The resulting compositions do not react with dry O2. Also, the invention relates to sodium silicide compositions having a powder X-ray diffraction pattern comprising at least three peaks with 2Theta angles selected from about 18.2, 28.5, 29.5, 33.7, 41.2, 47.4, and 56.2 and a solid state 23Na MAS NMR spectra peak at about 18 ppm. Moreover, the invention relates to methods of removing a volatile or flammable substance in a controlled manner. Furthermore, the alkali metal silicide compositions of the invention react with water to produce hydrogen gas.
An alkali metal silicide composition prepared by:
An alkali metal silicide composition having a 1:1 molar ratio of alkali metal to silicon wherein the alkali metal is selected from sodium or potassium and the alkali metal silicide composition is stable in dry air.
Dependencies are inferred from the claim text.