High-strength cold-rolled steel sheet excellent in coating adhesion, workability and hydrogen embrittlement resistance, and steel component for automobile
AssigneeKobe Steel, Ltd.
InventorsMasaaki Miura, Shinji Kozuma, Yoichi Mukai, Yoshinobu Omiya
Life of this patent
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Abstract
A cold rolled steel sheet satisfying on the basis of percent by mass the chemical composition of 0.06-0.6% C, 0.1-2% Si, 0.01-3% Al, 1-4% Si+Al, 1-6% Mn, Si/Mn≦0.40, in which there exists 10 or more pieces/100 μm2 of Mn—Si composite oxide having Mn—Si atom ratio (Mn/Si) of 0.5 or over and major axis of from 0.01 μm to 5 μm and also having a covering ratio of 10% or below at which the surface of the steel sheet is covered with oxide containing Si as the main component.
Claims29
A cold rolled steel sheet wherein
- said cold rolled steel sheet has a chemical composition comprising, on the basis of percent by mass:
- C ranging from 0.06 to 0.6%;
- Si ranging from 0.1 to 2%;
- Al ranging from 0.07 to 3%;
- Si+Al ranging from 1 to 4%;
- Mn ranging from 1 to 6%;
- S of 0.02% or less;
- N of 0.01% or less;
- O of 0.01% or less;
- and
- the remainder being Fe and unavoidable impurities;
- wherein:
- Si/Mn≦0.40;
- said cold rolled steel sheet has, in the surface of said steel sheet, 10 or more pieces/100 μm2 of Mn—Si composite oxide of which a Mn—Si atom ratio (Mn/Si) is 0.5 or over and a major axis is from 0.01 μm to 5 μm, and has a covering ratio of 10% or below wherein the surface of said steel sheet is covered with oxide comprising Si as the main component;
- and
- said cold rolled steel sheet comprises, on the basis of the total volume fraction of the steel:
- 40% or over bainitic ferrite;
- from 1 to 50% polygonal ferrite;
- and
- from 3% to 25% retained austenite,
- wherein a combined fraction of bainitic ferrite and polygonal ferrite is 75% or more and the tensile strength of the steel sheet is 780 MPa or higher.
A cold rolled steel sheet,
- wherein said cold rolled steel sheet has a chemical composition comprising, on the basis of percent by mass:
- C ranging from 0.06 to 0.6%;
- Si ranging from 0.1 to 2%;
- Al ranging from 0.07 to 3%;
- Si+Al ranging from 1 to 4%;
- Mn ranging from 1 to 6%;
- S of 0.02% or less;
- N of 0.01% or less;
- O of 0.01% or less;
- and
- the remainder being Fe and unavoidable impurities;
- wherein:
- and
- Si/Mn≦0.40;
- said cold rolled steel sheet has in the surface of said steel sheet, 10 or more pieces/100 μm2 of Mn—Si composite oxide of which a Mn—Si atom ratio (Mn/Si) is 0.5 or over and a major axis is from 0.01 μm to 5 μm, and has a covering ratio of 10% or below wherein the surface of said steel sheet is covered with oxide comprising Si as a main component;
- and said cold rolled steel sheet comprises, on the basis of the total volume fraction of the steel:
- 50% or over tempered martensite;
- from 4 to 40% ferrite;
- and
- from 3 to 25% retained austenite
- wherein a combined fraction of tempered martensite and ferrite is 75% or more and the tensile strength of the steel sheet is 780 MPa or higher.
A cold rolled steel sheet, wherein
- said cold rolled steel sheet has a chemical composition comprising, on the basis of percent by mass:
- C ranging from 0.06 to 0.6%;
- Si ranging from 0.1 to 2%;
- Al ranging from 0.07 to 3%;
- Si+Al ranging from 1 to 4%;
- Mn ranging from 1 to 6%;
- S of 0.02% or less;
- N of 0.01% or less;
- O of 0.01% or less;
- and
- the remainder being Fe and unavoidable impurities;
- wherein:
- Si/Mn≦0.40;
- said cold rolled steel sheet comprises, on the basis of the total volume fraction of the steel:
- 40% or over bainitic ferrite;
- from 1 to 50% polygonal ferrite;
- and
- from 3% to 25% retained austenite,
- wherein a combined fraction of bainitic ferrite and polygonal ferrite is 75% or more, the tensile strength of the steel sheet is 780 MPa or higher;
- and there exists no crack of 3 μm or less in width and 5 μm or over in depth in any 10 fields of view when observation at 2000× magnification by SEM is made of a cross section in the proximity of the surface of said steel sheet.
A cold rolled steel sheet, wherein
- said cold rolled steel sheet has a chemical composition comprising, on the basis of percent by mass:
- C ranging from 0.06 to 0.6%;
- Si ranging from 0.1 to 2%;
- Al ranging from 0.07 to 3%;
- Si+Al ranging from 1 to 4%;
- Mn ranging from 1 to 6%;
- S of 0.02% or less;
- N of 0.01% or less;
- O of 0.01% or less;
- and
- the remainder being Fe and unavoidable impurities;
- wherein:
- Si/Mn≦0.40;
- said cold rolled steel sheet comprises, on the basis of the total volume fraction of the steel:
- 50% or over tempered martensite;
- from 4 to 40% ferrite;
- and
- from 3 to 25% retained austenite;
- wherein a combined fraction of tempered martensite and ferrite is 75% or more, the tensile strength of the steel sheet is 780 MPa or higher;
- and there exists no crack of 3 μm or less in width and 5 μm or over in depth in any 10 fields of view when observation at 2000× magnification by SEM is made of a cross section in the proximity of the surface of said steel sheet.
Dependencies are inferred from the claim text.