Latex resin composition for rubber gloves without sulfur and vulcanization acceleator and method of manufacturing dip-formed article using the composition

A latex resin composition for rubber gloves comprising monomers to be polymerized, the monomers are (a) a conjugated diene monomer;

• (b) an ethylenically unsaturated nitrile monomer;
• (c) an ethylenically unsaturated acid monomer;
• (d) an ethylenically unsaturated monomer copolymerizable with the ethylenically unsaturated nitrile monomer and the ethylenically unsaturated acid monomer;
• and (e) a reactive compound having two or more reactive groups,
• wherein the molecular weight of the reactive compound having two or more groups is 250 or more,
• wherein the reactive compound having two or more reactive groups is poly (tetramethylene ether) glycol diglycidyl ether, a compound of 3-alkoxy-2-hydroxy propyl acrylate having an alkoxy group composed of twelve carbon atoms and thirteen carbon atoms, propylene glycol polybutylene glycol monoacrylate, or a combination thereof,
• wherein the latex resin composition excludes both vulcanization accelerator and sulfur, and
• wherein the content of the composition includes 40-90 weight % of the conjugated diene monomer;
• 9-50 weight % of the ethylenically unsaturated nitrile monomer;
• 0.1-10 weight % of the ethylenically unsaturated acid monomer;
• 0.1-20 weight % of the ethylenically unsaturated monomer copolymerizable with the ethylenically unsaturated nitrile monomer and the ethylenically unsaturated acid monomer;
• and 0.1-5 weight % of the reactive compound having two or more reactive groups.