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US 8,957,178 B2Granted
Method for preparing condensation resins and use thereof
AssigneeBASF SE
InventorsGabor Börzsönyi, Günter Scherr, Klaus Menzel, Stefan Meuer
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Abstract
The present invention relates to new condensation resins of urea, formaldehyde, and CH-acidic aldehydes, to methods for preparing them, and to their use.
Claims15
A method for reducing viscosity of a condensation resin, the method comprising:
- reacting a substantially fully reacted, solidified condensation resin in need thereof with a monofunctional alcohol in the presence of BrØnsted acid,
- wherein the substantially fully reacted condensation resin is synthesized from one molar part of at least one urea, from 3.8 to 9 molar parts formaldehyde, and from 3.8 to 9 molar parts of at least one CH-acidic aldehyde, and
- wherein the at least one urea, formaldehyde, and the at least one CH-acidic aldehyde in the substantially fully reacted condensation resin have undergone reaction with one another to an extent of at least 95%.
A method for preparing a condensation resin and for reducing a viscosity thereof, the method comprising:
- reacting one molar part of at least one urea, from 3.8 to 9 molar parts formaldehyde, and from 3.8 to 9 molar parts of at least one CH-acidic aldehyde, at a temperature between 60 and 150° C. in the presence of an acid, a base, or any combination thereof, and optionally further in the presence of a solvent, a diluent, or any combination thereof, thereby obtaining a condensation resin;
- then
- neutralizing the acid, base, or combination thereof;
- distillatively removing a volatile constituent;
- and
- subsequently reacting the solidified condensation resin in need thereof with a monofunctional alcohol in the presence of an acid, thereby reducing a viscosity of the condensation resin,
- wherein the at least one urea is a urea of formula (I), a urea of formula (II), or any combination thereof:
- R1and R2 are each independently hydrogen or a C1-C20 alkyl radical,
- A is a C1-C20 alkylene radical,
- X is oxygen or sulfur, the at least one CH-acidic aldehyde is of formula (III):
- and
- R3 and R4 are each independently an alkyl, cycloalkyl, aryl, or alkylaryl radical, or R3 and R4 together optionally form a ring.
9 more elements
Dependencies are inferred from the claim text.