System and method for creating a bipolar resistive RAM (RRAM)

A resistive memory having a plurality of resistive elements, wherein a resistance of each resistive memory element changes with respect to a state of the resistive memory element, the resistive memory comprising:

• a substrate;
• a first memory access device formed on the substrate;
• a first contact formed on the first memory access device;
• a first resistive memory element formed on the first contact, wherein the first resistive memory element has a first polarity, and wherein the first memory access device provides read access and write access to the state of the first resistive memory element;
• a second memory access device formed on the substrate;
• a second contact formed on the second memory access device;
• a second resistive memory element formed on the second contact, wherein the second resistive memory element has a second polarity that is opposite to the first polarity of the first resistive memory element, and wherein the second memory access device provides read access and write access to the state of the second resistive memory element;
• a first bottom electrode and a second bottom electrode formed above the first contact and the second contact, respectively;
• and
• a first top electrode and a second top electrode formed above the first bottom electrode and the second bottom electrode, respectively, wherein
• the first resistive memory element includes
• a first transitional metal oxide (TMO) layer formed on the first bottom electrode,
• a first reactive metal layer formed on the first TMO layer and below the first top electrode, and
• the second resistive memory element includes
• a second reactive metal layer formed on the second bottom electrode, and
• a second TMO layer formed on the first reactive metal layer and below the second top electrode.

A resistive memory having a plurality of resistive elements, wherein a resistance of each resistive memory element changes with respect to a state of the resistive memory element, the resistive memory comprising:

• a substrate;
• a first memory access device formed on the substrate;
• a first contact formed on the first memory access device;
• a first resistive memory element formed on the first contact, wherein the first resistive memory element has a first polarity, and wherein the first memory access device provides read access and write access to the state of the first resistive memory element;
• a second memory access device formed on the substrate;
• a second contact formed on the second memory access device;
• and
• a second resistive memory element formed on the second contact, wherein the second resistive memory element has a second polarity that is opposite to the first polarity of the first resistive memory element, and wherein the second memory access device provides read access and write access to the state of the second resistive memory element, wherein
• the first resistive memory element is configured to i) receive a first voltage from a first direction and a second voltage from a second direction to set the first resistive memory element, ii) receive the second voltage from the first direction and the first voltage from the second direction to reset the first resistive memory element, and iii) receive a third voltage from the first direction to read the first resistive memory element, and
• the second resistive memory element is configured to i) receive the second voltage from the first direction and the first voltage from the second direction to set the second resistive memory element, ii) receive the second voltage from the second direction and the first voltage from the first direction to reset the second resistive memory element, and iii) receive the third voltage from the second direction to read the second resistive memory element.

A resistive memory having a plurality of resistive elements, wherein a resistance of each resistive memory element changes with respect to a state of the resistive memory element, the resistive memory comprising:

• a substrate;
• a first memory access device formed on the substrate;
• a first contact formed on the first memory access device;
• a first resistive memory element formed on the first contact, wherein the first resistive memory element has a first polarity, and wherein the first memory access device provides read access and write access to the state of the first resistive memory element;
• a second memory access device formed on the substrate;
• a second contact formed on the second memory access device;
• a second resistive memory element formed on the second contact, wherein the second resistive memory element has a second polarity that is opposite to the first polarity of the first resistive memory element, and wherein the second memory access device provides read access and write access to the state of the second resistive memory element,
• wherein the first resistive memory element includes a first transitional metal oxide (TMO) layer and the second resistive memory element includes a second TMO layer,
• wherein the first TMO layer and/or the second TMO layer includes Hf0x, and
• wherein x is less than 2;
• and
• a first transition layer formed between (i) the first TMO layer and (ii) a first reactive metal layer, and/or a second transition layer formed between (i) the second TMO layer and (ii) a second reactive metal layer, wherein the first transition layer and the second transition layer include donor oxygen atoms.

A method of forming a resistive memory having a plurality of resistive elements, wherein a resistance of each resistive memory element changes with respect to a state of the resistive memory element, the method comprising:

• providing a substrate;
• forming a first memory access device and a second memory access device on the substrate;
• forming a first contact on the first memory access device and forming a second contact on the second memory access device;
• forming a first resistive memory element on the first contact, wherein the first resistive memory element has a first polarity, and wherein the first memory access device provides read access and write access to the state of the first resistive memory element;
• forming a second resistive memory element on the second contact, wherein the second resistive memory element has a second polarity that is opposite to the first polarity of the first resistive memory element, and wherein the second memory access device provides read access and write access to the state of the second resistive memory element;
• wherein forming the first resistive memory element includes forming a first transitional metal oxide (TMO) layer between (i) a first reactive metal layer and (i) a first bottom electrode, and
• wherein forming the second resistive memory element includes forming a second reactive metal layer between (i) a second TMO layer and (ii) a second bottom electrode.

A method of forming a resistive memory having a plurality of resistive elements, wherein a resistance of each resistive memory element changes with respect to a state of the resistive memory element, the method comprising:

• providing a substrate;
• forming a first memory access device and a second memory access device on the substrate;
• forming a first contact on the first memory access device and forming a second contact on the second memory access device;
• forming a first resistive memory element on the first contact, wherein the first resistive memory element has a first polarity, and wherein the first memory access device provides read access and write access to the state of the first resistive memory element;
• and
• forming a second resistive memory element on the second contact, wherein the second resistive memory element has a second polarity that is opposite to the first polarity of the first resistive memory element, and wherein the second memory access device provides read access and write access to the state of the second resistive memory element,
• wherein forming the first resistive memory element and the second resistive memory element comprises:
• forming a first bottom electrode and a second bottom electrode above the first contact and the second contact, respectively;
• and
• forming a first top electrode and a second top electrode above the first bottom electrode and the second bottom electrode, respectively, wherein
• the first resistive memory element includes
• a first transitional metal oxide (TMO) layer formed on the first bottom electrode,
• a first reactive metal layer formed on the first TMO layer and below the first top electrode, and
• the second resistive memory element includes
• a second reactive metal layer formed on the second bottom electrode, and
• a second TMO layer formed on the first reactive metal layer and below the second top electrode.

A method of forming a resistive memory having a plurality of resistive elements, wherein a resistance of each resistive memory element changes with respect to a state of the resistive memory element, the method comprising:

• providing a substrate;
• forming a first memory access device and a second memory access device on the substrate;
• forming a first contact on the first memory access device and forming a second contact on the second memory access device;
• forming a first resistive memory element on the first contact, wherein the first resistive memory element has a first polarity, and wherein the first memory access device provides read access and write access to the state of the first resistive memory element;
• and
• forming a second resistive memory element on the second contact, wherein the second resistive memory element has a second polarity that is opposite to the first polarity of the first resistive memory element, and wherein the second memory access device provides read access and write access to the state of the second resistive memory element, wherein
• the first resistive memory element is configured to i) receive a first voltage from a first direction and a second voltage from a second direction to set the first resistive memory element, ii) receive the second voltage from the first direction and the first voltage from the second direction to reset the first resistive memory element, and iii) receive a third voltage from the first direction to read the first resistive memory element, and
• the second resistive memory element is configured to i) receive the second voltage from the first direction and the first voltage from the second direction to set the second resistive memory element, ii) receive the second voltage from the second direction and the first voltage from the first direction to reset the second resistive memory element, and iii) receive the third voltage from the second direction to read the second resistive memory element.

A method of forming a resistive memory having a plurality of resistive elements, wherein a resistance of each resistive memory element changes with respect to a state of the resistive memory element, the method comprising:

• providing a substrate;
• forming a first memory access device and a second access device on the substrate;
• forming a first contact on the first memory access device and forming a second contact on the second memory access device;
• forming a first resistive memory element on the first contact, wherein the first resistive memory element has a first polarity, and wherein the first memory access device provides read access and write access to the state of the first resistive memory element;
• forming a second resistive memory element on the second contact, wherein the second resistive memory element has a second polarity that is opposite to the first polarity of the first resistive memory element, and wherein the second memory access device provides read access and write access to the state of the second resistive memory element,
• wherein the first resistive memory element includes a first transitional metal oxide (TMO) layer and the second resistive memory element includes a second TMO layer,
• wherein the first TMO layer and/or the second TMO layer includes Hf0x, and
• wherein x is less than 2;
• and
• forming a first transition layer between (i) the first TMO layer and (ii) the first reactive metal layer, and/or forming a second transition layer between (i) the second TMO layer and (ii) the second reactive metal layer, wherein the first transition layer and the second transition layer include donor oxygen atoms.