Method for producing polyether carbonate polyols
AssigneeBayer Intellectual Property GmbH
InventorsChristoph Gürtler, Jörg Hofmann, Aurel Wolf, Stefan Grasser
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Abstract
The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter substances, one or more alkylene oxides and carbon dioxide in the presence of at least one double metal cyanide catalyst, wherein the cyanide-free metal salt, the metal cyanide salt or both the mentioned salts used for the preparation of the double metal cyanide catalyst contain(s) from 0.3 to 1.8 mol base equivalents (based on 1 mol of the metal cyanide salt used for the synthesis of the catalyst) of alkaline metal hydroxide, metal carbonate and/or metal oxide.
Claims11
A process for preparing a polyether carbonate polyol consisting of reacting one or more H-functional starter substances, one or more alkylene oxides, and carbon dioxide in the presence of at least one double metal cyanide catalyst prepared from a cyanide-free metal salt and a potassium hexacyanocobaltate(III) salt, wherein said cyanide-free metal salt and/or said potassium hexacyanocobaltate(III) salt comprises from 0.3 to 1.8 mol base equivalents, based on 1 mol of said metal cyanide salt, of an alkaline metal hydroxide, metal carbonate, and/or metal oxide, wherein said at least one double metal cyanide catalyst is prepared by reacting an aqueous solution of said cyanide-free metal salt with an aqueous solution of said potassium hexacyanocobaltate(III) salt in the presence of one or more organic complex ligands, wherein said aqueous solution of said cyanide-free metal salt and/or said aqueous solution of said potassium hexacyanocobaltate(III) salt comprises one or more alkaline metal hydroxides, metal carbonates, and/or metal oxides, and wherein the total amount of said one or more alkaline metal hydroxides, metal carbonates, and/or metal oxides used is in the range of from 0.3 to 1.8 mol base equivalents, based on 1 mol of the potassium hexacyanocobaltate(III) salt.
Dependencies are inferred from the claim text.